A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
e. _The effect of Imperfect Fixation._--The earlier Photographers did not
always succeed in properly fixing their prints, since old Photographs are
often found thickly studded with spots and blotches in the tissue of the
paper. These prints however are not invariably faded upon the surface,
and hence it cannot be said that imperfect fixation will certainly end
in the total destruction of the picture. Still a notice of the subject
may properly be introduced in this place, and the attention of the reader
be once more drawn to the importance of washing the print in water on
removing it from the printing frame; a decomposition invariably occurring
when paper Positives _saturated with free Nitrate of Silver_ are plunged
in a dilute solution of Hyposulphite of Soda, containing an insufficient
quantity of the salt to dissolve away the Hyposulphite of Silver before it
begins to undergo spontaneous change.
f. _Exposure to an impure Atmosphere as a cause of Fading._--The five
causes of fading which precede, have mostly reference to an intrinsically
faulty condition of the print. This, the sixth, explains the mode in which
a Photograph carefully prepared may yet suffer injury from deleterious
matters often present in the atmosphere. The air of large cities, and
particularly that emanating from sewers and drains, contains Sulphuretted
Hydrogen, and hence articles of silver-plate become tarnished unless
placed beneath glass. The injury which a print sustains by exposure to
air contaminated with Sulphuretted Hydrogen, is less than the tarnish
produced upon the bright surface of a silver plate (see p. 148); but it
is recommended as a precautionary measure, that Photographic Pictures be
protected by glass or kept in a portfolio, and that they be not exposed
too freely to the air.
The products of the combustion of coal-gas are probably more likely than
the cause last named, to be a source of injury to Photographs suspended
without any covering. The sulphur compounds in gas burn into Sulphurous
and Sulphuric Acids, the latter of which, in combination with Ammonia,
produces the sparkling crystals often observed upon the shop windows.
The question as to the manner in which the Photographic Image may best be
protected from these extraneous causes of fading has been mooted, and many
plans of coating prints with some impervious material have been devised.
If the pictures are to be glazed or kept in a portfolio, this of itself
will be sufficient, but in other cases it may perhaps be useful to apply a
layer of spirit or gutta-percha varnish. The use of wax, resin, and such
bodies is likely, by introducing impurities, to act injuriously rather
than otherwise.
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