A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
g. _Decomposition of Pyroxyline a source of Injury to Collodion
Photographs._--Collodion Positives and Negatives are usually esteemed
permanent; but some have been exhibited which, having been put away in a
damp place, gradually became pale and indistinct. The change commences at
rough edges and isolated points, leaving the centre, as a rule, the last
affected. On examination, numerous cracks are often visible, thus seeming
to indicate that the Collodion film has undergone decomposition. The
result of this would be the liberation of corrosive Oxides of Nitrogen,
which destroy the image. Substitution compounds containing Peroxide of
Nitrogen are known to be liable to spontaneous change. The bitter resin
produced by acting upon white sugar with Nitro-Sulphuric Acid, if not kept
perfectly dry, will sometimes evolve enough gas to destroy the cork of the
bottle in which it is kept; the solution of the resin has then a strong
acid reaction, and rapidly fades an ordinary Positive Print.
These facts are interesting, and indicate that Collodion Pictures,
containing in themselves the elements of their destruction, should be
protected from moisture by a coating of varnish.
_Comparative Permanence of Photographic Prints._--There is every reason
to think that the Photographic Image, however formed, is permanent, if
certain injurious conditions are avoided;--in other words, that prints do
not necessarily fade, in the same manner as fugitive colours, by a simple
exposure to light and air. But supposing a case, which is the common
one, of injurious influences which cannot altogether be removed, it may
be useful to inquire what mode of printing gives the greatest amount of
stability.
Positives produced by a short exposure to light and subsequent
development with Gallic Acid, may be expected to be more permanent than
ordinary sun-prints; not that there is any reason to suppose the chemical
composition of a developed image to be peculiar, but that the use of the
Gallic Acid enables us to increase the intensity of the red picture first
formed, and to add to its stability by precipitating fresh Silver upon
it. This point has not always been attended to. It has been recommended
to remove the print from the developing solution whilst in the _red_ and
early stage of development, and to produce the dark tones subsequently by
means of gold; but this plan, although giving very good results as regards
colour and gradation of tone, appears to lessen the advantage which would
otherwise accrue from the adoption of a Negative process, and to leave the
picture, as regards permanency, much in the condition of an ordinary print
obtained by direct action of light.
The original Talbotype process, in which the latent image is formed upon
Iodide of Silver, produces, next to Collodion, the most stable image; but
the difficulty of obtaining bright and warm tints on Iodide of Silver,
will stand in the way of its adoption.
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