A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The _toning_ of Paper Positives is the part of the process which is likely
to injure their stability; inasmuch as the finest results cannot easily be
obtained without incurring _sulphuration_, and the action of Sulphur, if
carried to any extent, has been shown to be detrimental. The point to be
kept in view, is to alter the original structure of the image as little as
possible in toning; and it is best to use Gold in preference to Sulphur
as the colouring agent. On theoretical grounds, toning by an alkaline
solution of Chloride of Gold (p. 132), and fixing by Ammonia, is the best
process; but the employment of Sel d'or, which gives a more agreeable
colour and has not been found practically to injure the image, will be
generally preferred. In using _a single fixing and toning Bath_ the same
object of working by Gold rather than by Sulphur may be best attained by
maintaining the activity of the Bath by constant additions of Chloride of
Gold.
The prints which are _least stable_ are such as have been toned in _acid
Hyposulphite Baths, without Gold;_ and the difficulty of preserving such
pictures from becoming yellow in the half-tones is very great. Possibly
a portion of the Sulphuretted Acid may unite with the Suboxide of Silver
and cannot be removed by washing (see p. 158); but even if this be not
the case, it is certain that no ordinary amount of care will obviate the
occasional occurrence of fading, unless the Hyposulphite Bath be kept
_neutral to test-paper_. And all those plans of toning in which Acetic or
Hydrochloric Acid is mixed with Hyposulphite of Soda, and the Positive
immersed whilst the liquid is in a milky state from precipitation of
Sulphur, ought studiously to be avoided.
It will be well also to avoid pushing the action of the fixing and toning
Bath to its utmost limits, since practice and theory both teach us that
the Positives which have been long in the Hyposulphite, and consequently
show a tendency to yellowness in the light parts, are most liable to
lose their half-tones on keeping. Photographic Prints are found often to
_darken_ slightly in the course of years; and therefore by suspending the
toning action at an earlier stage a margin is left for what some have
termed "an improvement by time."
The use of _Albuminized_ in preference to plain paper gives an advantage
in protecting the image from oxidation; but if constantly exposed to
moisture, a putrefactive decomposition of the animal matter may occur. The
proper colour of the Albumen image being a _pale red_, the black tones
should not be sought for on that variety of paper: their production,
if Hyposulphite of Soda were used in toning, would probably imply an
amount of Sulphuration which would more than counterbalance any advantage
otherwise derivable from the Albumen.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account