A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
After the polishing is complete, the plate is ready to receive the
sensitive coating. This part of the process is conducted in a peculiar
manner. A simple piece of cardboard or a thin sheet of wood, previously
soaked in solution of Iodine, evolves enough of the vapour to attack the
silver plate; which being placed immediately above, and allowed to remain
for a short time, acquires a pale violet hue, due to the formation of
_an excessively delicate layer_ of Iodide of Silver. By prolonging the
action of the Iodine the violet tint disappears and a variety of prismatic
colours are produced, much in the same way as when light is decomposed
by thin plates of mica or the surface of mother-of-pearl. From violet
the plate becomes of a straw-yellow, then rose-colour, and afterwards
steel-grey. By continuing the exposure, the same sequence of tints is
repeated; the steel-grey disappears, and the yellow and rose-colours
recur. The deposit of Iodide of Silver gradually increases in thickness
during these changes; but to the end it remains excessively thin and
delicate. In this respect it contrasts strongly with the dense and creamy
layer often employed in the Collodion process, and shows that a large
proportion of the Iodide of Silver must in such a case be superfluous, as
far as any influence produced by the light is concerned. An inspection
of a sensitive Daguerreotype plate reveals the microscopic nature of the
actinic changes involved in the Photographic Art, and teaches a useful
lesson.
_Increase of sensibility obtained by combining the joint action of Bromine
and Iodine._--The original process of Daguerre was conducted with the
vapour of Iodine only; but in the year 1840 it was discovered by Mr. John
Goddard that the sensibility of the plate was greatly promoted by exposing
it to the vapours of Iodine and Bromine in succession,--the proper time
for each being regulated by the tints assumed.
The composition of this Bromo-Iodide of Silver, so called, is uncertain,
and has not been proved to bear any analogy to that of the mixed salt
obtained by decomposing a solution of Iodide and Bromide of Potassium with
Nitrate of Silver. Observe also that the Bromo-Iodide of Silver is more
sensitive than the simple Iodide _only token the vapour of Mercury is
employed as a developer_. M. Claudet proves that if the image be formed by
the direct action of light alone (see page 174), the usual condition is
reversed, and that the use of Bromine under such circumstances retards the
effect.
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