A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
There are two modes of iodizing and sensitizing the sheets: first, by
floating alternately upon Iodide of Potassium and Nitrate of Silver, in
the same manner as in the preparation of papers for Positive Printing;
and second, by what is termed "the single wash," which is thought by many
to give superior results as regards sensitiveness and intensity of image.
To iodize by this mode, the yellow Iodide of Silver, prepared by mixing
solutions of Iodide of Potassium and Nitrate of Silver, is dissolved in
a strong solution of Iodide of Potassium; the sheets are floated for an
instant upon this liquid and dried; they are then removed to a dish of
water, by the action of which the Iodide of Silver is precipitated upon
the surface of the paper in a finely divided state.
The properties of a solution of Iodide of Silver in Iodide of Potassium,
or of the double Iodide of Potassium and Silver, are described at page 43,
a reference to which will show that the double salt is decomposed by a
large quantity of water, with precipitation of the Iodide of Silver, this
substance being insoluble in a dilute solution of Iodide of Potassium,
although soluble in a strong solution.
Paper coated with Iodide of Silver by this mode, after proper washing in
water to remove soluble salts (which if allowed to remain would attract
damp), will keep good for a long time. The layer of Iodide appears of a
pale primrose colour, and is perfectly insensitive to light. Even exposure
to the sun's rays produces no change, thus indicating that an excess of
Nitrate of Silver is essential to the visible darkening of Iodide of
Silver by light. The paper is also insensitive to the reception of an
invisible image, differing in this respect from the washed Collodion
plate, which receives an impression in the Camera, although apparently
freed from Nitrate of Silver.
To render Calotype paper sensitive to light, it is brushed with a solution
of Nitrate of Silver containing both Acetic and Gallic Acids, termed
"Aceto-Nitrate" and "Gallo-Nitrate" solution. The Gallic Acid lessens
the keeping qualities of the paper, but increases the sensitiveness.
The Acetic Acid prevents the paper from blackening all over during
the development, and preserves the clearness of the white parts; its
employment is indispensable.
The paper is commonly excited upon the morning of the day upon which it
is intended to be used; and the longer it is kept, the less active and
certain it becomes. An exposure of five to eight minutes in the Camera is
the average time with an ordinary view lens.
The picture is developed with a saturated solution of Gallic Acid, to
which a portion of Aceto-Nitrate of Silver is added to heighten the
intensity. Both Sulphate of Iron, and Pyrogallic Acid have also been used,
but they are unnecessarily strong, the invisible image being more easily
developed upon paper than upon Collodion (see page 143).
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