A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Nitric Acid is a powerful solvent for the metallic bodies generally. To
illustrate its action in that particular, as contrasted with other acids,
place pieces of silver-foil in two test-tubes, the one containing dilute
Sulphuric, the other dilute Nitric Acid; on the application of heat a
violent action soon commences in the latter, but the former is unaffected.
In order to understand this, it must be borne in mind that when a metallic
substance dissolves in an acid, the nature of the solution is different
from that of an aqueous solution of salt or sugar. If salt water be boiled
down until the whole of the water has evaporated, the salt is recovered
with properties the same as at first; but if a similar experiment be made
with a solution of Silver in Nitric Acid, the result is different: in that
case metallic Silver is not obtained on evaporation, but Silver combined
with Oxygen and Nitric Acid, both of which are strongly retained, being in
fact in a state of chemical combination with the metal.
If we closely examine the effects produced by treating Silver with Nitric
Acid, we find them to be of the following nature:--first, a certain
amount of Oxygen is imparted to the metal, so as to form an _Oxide_, which
Oxide dissolves in another portion of the Nitric Acid, producing _Nitrate_
of the Oxide, or, as it is shortly termed, Nitrate of Silver.[1]
[1] The preparation of Nitrate of Silver from the standard coin of the
realm is described in Part III., Art. "Silver."
It is the instability of Nitric Acid therefore--its proneness to part with
Oxygen--which renders it superior to the Sulphuric and to most acids in
dissolving Silver and various other substances, both organic and inorganic.
_Properties of Nitrate of Silver._--In preparing Nitrate of Silver, when
the metal has dissolved, the solution is boiled down and set aside to
crystallize. The salt however as so obtained is still acid to test-paper,
and requires either re-crystallization, or careful heating to about 300°
Fahrenheit. It is this retention of small quantities of Nitric Acid, and
sometimes probably of Nitrous Acid, which renders much of the commercial
Nitrate of Silver useless for Photography, until rendered neutral by
fusion and a second crystallization.
Pure Nitrate of Silver occurs in the form of white crystalline plates,
which are very heavy and dissolve readily in an equal weight of cold
water. The solubility is much lessened by the presence of free Nitric
Acid, and in the _concentrated_ Nitric Acid the crystals are almost
insoluble. Boiling Alcohol takes up about one-fourth part of its weight
of the crystallized Nitrate, but deposits nearly the whole on cooling.
Nitrate of Silver has an intensely bitter and nauseous taste; acting as a
caustic, and corroding the skin by a prolonged application. Its aqueous
solution does not redden blue litmus-paper.
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