A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
When the Collodion is properly cleared from sediment, the operator takes
a glass plate, previously cleaned, and wipes it gently with a silk
handkerchief, in order to remove any particles of dust which may have
subsequently collected. If it be a plate of moderate size, it may be
held by the corners in a horizontal position, between the forefinger and
thumb of the left hand. The Collodion is to be poured on steadily until a
circular pool is formed, extending nearly to the edges of the glass.
[Illustration]
By a slight inclination of the plate the fluid is made to flow towards the
corner marked 1, in the above diagram, until it nearly touches the thumb
by which the glass is held: from corner 1 it is passed to corner 2, held
by the forefinger; from 2 to 3, and lastly, the excess poured back into
the bottle from the corner marked No. 4. It is then to be held vertically
over the bottle for a moment, until it _nearly_ ceases to drip, and then,
by raising the thumb a little, the direction of the plate is changed,
so as to cause the diagonal lines to coalesce and produce a smooth
surface. The operation of coating a plate with Collodion must not be done
hurriedly, and nothing is required to ensure success but steadiness of
hand and a sufficiency of the fluid poured in the first instance upon the
plate.
In coating larger plates, the _pneumatic_ holder, which fixes itself by
suction, will be found the most simple and useful.
_The Proper Time for immersing the Film in the Bath._--After exposing a
layer of Collodion to the air for a short time, the greater part of the
Ether evaporates, and leaves the Pyroxyline in a state in which it is
neither wet nor dry, but receives the impression of the finger without
adhering to it. Photographers term this _setting_, and when it takes
place it is a sign that the time has come for submitting it to the action
of the Bath.
If the film be lowered into the Nitrate before it has set, the effect is
the same as that produced by adding Water to Collodion. The Pyroxyline is
precipitated in part, and consequently there are cracks, and the developer
will not always run up to the edge of the film. On the other hand, if
it be allowed to become too dry, the Iodide of Silver does not form
perfectly, and the film, on being washed and brought out to the light,
exhibits a peculiar iridescent appearance, and is paler in some parts than
in others.
No rule can be given as to the exact time which ought to elapse: it varies
with the temperature of the atmosphere, and with the proportions of Ether
and of Pyroxyline; thin Collodion containing but little Alcohol requiring
to be immersed more speedily. Twenty seconds in the common way, or ten
seconds in hot weather, will be found an average time.
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