A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
With ordinary Negative Collodion, an addition of Nitrate of Silver to the
developer will often be required; but the Pyrogallic Acid is to be used
alone until the image has reached its maximum of intensity, which it will
do in a minute or so, according to the temperature of the developing room.
The plate may then be examined leisurely by placing it in front of, and
at some distance from, a sheet of white paper. If it is not sufficiently
black, add about four drops of the Nitrate Bath to each drachm of
developer, stir well with a glass rod, and continue the action until the
requisite amount of intensity is obtained. When there is any disposition
in the plate to _fog_ towards the end of the development, it may be
obviated by fixing with Cyanide of Potassium (not Hyposulphite), and then,
after a careful washing, intensifying with Pyrogallic Acid and Nitrate
of Silver in the usual way. The glass which contains the mixture of
Pyrogallic Acid and Nitrate of Silver must be washed out after each plate,
as the black deposit hastens the discoloration of the fresh solution (p.
179).
_Appearance of the Negative image during and after the reducing process,
as a guide to the exposure to light._--An under-exposed plate developes
slowly. By continuing the action of the Pyrogallic Acid, the high lights
_become very black_, but the shadows are invisible, nothing but the yellow
Iodide being seen on those portions of the plate. After treatment with the
Cyanide, the picture shows well as a Positive, but by transmitted light
all the minor details are invisible; the image is black and white, without
any half-tone.
An over-exposed Negative developes rapidly at first, but soon begins
to blacken slightly at every part of the plate. After the fixing is
completed, nothing can often be seen by reflected light but a uniform
grey surface of metallic Silver, without any appearance (or, at most, an
indistinct one) of an image. By transmitted light the plate may appear of
a red or brown colour, and the image is _faint_ and dull. The clear parts
of the Negative being obscured by the fogging, and the half-shadows having
acted so long as nearly to overtake the lights, there is a want of proper
_contrast;_ hence the over-exposed plate is the exact converse of the
under-exposed, where the contrast between lights and shadows is too well
marked, from the absence of intermediate tints.
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