A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
A Negative which has received the proper amount of exposure,
usually possesses the following characters after the development is
completed:--The image is partially but not fully seen by reflected light.
In the case of a portrait, any dark portions of drapery show well as a
Positive, but the features of the sitter are scarcely to be discerned.
The plate has a general aspect as of fogging _about to commence_, but
not actually established. By transmitted light the figure is bright, and
appears to stand out from the glass: the dark shadows are clear, without
any misty deposit of metallic Silver; the high lights black _almost_ to
complete opacity. The _colour_ of the image however varies much with the
state of the Bath and Collodion and with the brightness of the light.
The remarks already made under the head of Positives, apply equally well
to Negatives; that is, it will be difficult to secure gradation of tone,
unless the object be _equally_ illuminated, without any strong contrast of
light and shade. Hence the direct rays of the sun are, as a rule, to be
avoided, and curtains, etc., employed when practicable.
FIXING AND VARNISHING THE IMAGE.
After the development is completed, and the plate has been carefully
washed by a stream of water, it may be brought out to the light and
treated with the Hyposulphite or Cyanide, until the unaltered Iodide is
entirely cleared off. Some use a Bath for the Cyanide; but it is doubtful
whether much saving is effected by doing so. The plate is again to be
carefully washed after the fixing; and especially if Hyposulphite of
Soda be used. Three or four minutes in running water will not be too
long, or the glass may be left in a dish of water for an hour or two. If
such precautions are neglected, crystals form on drying, and the image is
injured.
Collodion pictures should be protected by a coat of varnish, both
Negatives and Positives having been known to fade when exposed to damp air
without any covering (see p. 166). To prepare transparent varnish. Amber
may be dissolved in Chloroform according to Dr. Diamond's formula;--about
80 grains of amber-beads or pipe-stems should be digested with one ounce
of the Chloroform, and the clear portion separated by filtration. It may
be poured on the plate in the same manner as Collodion, and dries up
speedily into a hard and transparent layer. The Spirit Varnish ordinarily
sold for Negatives requires the aid of heat to prevent the gum from
chilling as it dries; the plate is first warmed gently and the varnish
poured on and off in the usual way; it is then, whilst still dripping,
held to the fire until the Spirit has evaporated. A few trials will render
the operation easy to perform. White Lac dissolved in strong Alcohol or in
Benzole has also been recommended for clear varnish.
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