A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
When prepared by the latter mode it forms an impalpable powder, the colour
of which varies slightly with the manner of precipitation. If the Iodide
of Potassium be in excess, the Iodide of Silver falls to the bottom of the
vessel nearly white; but with an excess of Nitrate of Silver it is of a
straw-yellow tint. This point may be noticed, because the yellow salt is
the one adapted for Photographic use, the other being insensible to the
influence of light.
Iodide of Silver is tasteless and inodorous; insoluble in water and in
dilute Nitric Acid. It is scarcely dissolved by Ammonia, which serves
to distinguish it from the Chloride of Silver, freely soluble in that
liquid. Hyposulphite of Soda and Cyanide of Potassium both dissolve Iodide
of Silver; it is also soluble in solutions of the alkaline Bromides and
Iodides, as will be further explained in Chapter IV.
Iodide of Silver is reduced by Metallic Zinc in the same manner as the
Chloride of Silver, forming soluble Iodide of Zinc and leaving a black
powder.
THE PREPARATION AND PROPERTIES OF BROMIDE OF SILVER.
This substance so closely resembles the corresponding salts containing
Chlorine and Iodine, that a short notice of it will suffice.
Bromide of Silver is prepared by exposing a silvered plate to the vapour
of Bromine, or by adding solution of Bromide of Potassium to Nitrate of
Silver. It is an insoluble substance, slightly yellow in colour, and
distinguished from Iodide of Silver by dissolving in strong Ammonia and in
Chloride of Ammonium. It is freely soluble in Hyposulphite of Soda and in
Cyanide of Potassium.
The properties of the element Bromine are described in Part III.
CHEMISTRY OF THE OXIDES OF SILVER.
_The Protoxide of Silver_ (Ag O).--If a little Potash or Ammonia be added
to solution of Nitrate of Silver, an olive-brown substance is formed,
which, on standing, collects at the bottom of the vessel. This is Oxide of
Silver, displaced from its previous state of combination with Nitric Acid
by the stronger oxide. Potash. Oxide of Silver is soluble to a very minute
extent in pure water, the solution possessing an alkaline reaction to
Litmus; it is easily dissolved by Nitric or Acetic Acid, forming a neutral
Nitrate or Acetate; also soluble in Ammonia (Ammonio-Nitrate of Silver),
and in Nitrate of Ammonia, Hyposulphite of Soda, and Cyanide of Potassium.
Long exposure to light converts it into a black substance, which is
probably a Suboxide.
_The Suboxide of Silver_ (Ag{2}O?)--This substance was obtained by Faraday
on exposing a solution of the Ammonio-Nitrate of Silver to the action of
the air. It bears a relation to the ordinary brown Protoxide of Silver
similar to that which the Subchloride bears to Protochloride of Silver.
Suboxide of Silver is a black or grey powder, which assumes the metallic
lustre on rubbing, and when treated with dilute Acids is resolved into
Protoxide of Silver which dissolves, and metallic Silver.
SECTION II.
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