A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The mode often followed is to immerse the Positive in the Hyposulphite
Bath in the state in which it comes from the printing-frame; moving it
about in the liquid in order to displace air-bubbles, which, if allowed
to remain, produce spots. But the Author, for reasons given in the first
part of the Work (pp. 129 and 165), recommends that the print should
first be washed in common water until the soluble Nitrate of Silver has
been removed.[47] This is known to be the case when the liquid flows
away clear; the first milkiness being caused by the soluble Carbonates
and Chlorides in the water precipitating the Nitrate of Silver. Greater
security is thus afforded that the print will be toned in a really
permanent manner, since after removing the Nitrate of Silver from the
proof, the Bath does not work quickly unless the supply of Gold be well
maintained.
[47] This water must be free from Hyposulphite of Soda, or the print will
become discoloured.
Immediately on coming in contact with the Hyposulphite of Soda in the
fixing and toning Bath, the chocolate brown or violet tint of the Positive
disappears, and leaves the image of a red tone. Albumen proofs become
brick-red; Ammonio-Nitrate a sepia or brown-black. If the colour is
unusually _pale_ at this stage, probably the Silver Bath is too weak, or
the quantity of Chloride of Ammonium or Sodium insufficient.
After the print has been thoroughly reddened, the _toning_ action begins,
and must be continued until the desired effect is obtained. This may
happen in from ten minutes to a quarter of an hour, if the solution is in
good working order and the thermometer at 60°; but much depends upon the
temperature, and the activity of the Bath. English papers, and especially
the same prepared with Albumen, tone more slowly than foreign papers plain
salted.
The brown and purple tints are an earlier stage of coloration than the
black tones, and therefore the latter require more time. It must be borne
in mind however that prolonged immersion in the Bath is favourable to
sulphuration and yellowness; tending also to render the image unstable
and liable to fade in the half-tones. This fading may not be seen
decidedly whilst the print is in the Bath, but will show itself in the
after-processes of washing and drying.
The ultimate colour of the Print will vary much with the density of the
Negative and the character of the subject; copies of line engravings,
having but little half-tone, are easily obtained of a dark shade
resembling the original impression.
Some advise that on removal from the toning Bath the Print should be
soaked in new Hyposulphite for ten minutes, to complete the fixation;
but this precaution is not required with a Bath of the strength given in
the formula. An analysis of an old Bath which had been extensively used,
indicated only ten grains of Hyposulphite of Silver to the ounce, so that
it was far from saturated.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account