A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The extent to which the development should be carried depends upon the
kind of Print desired. By pushing the action of the Gallic Acid, a dark
picture not much altered by the fixing Bath will be produced. But a better
result as regards colour and gradation of tone will be obtained by
removing the Print from the developing solution whilst in the light red
stage, and toning it subsequently by means of Gold; in which case it will
correspond both in appearance and properties to a Positive obtained by the
direct action of light (see the remarks at page 167).
When it is intended to follow the latter plan, the action of the developer
must be stopped at a point when the proof appears lighter than it is to
remain; since the Sel d'or Bath adds a little to the intensity, and the
image becomes somewhat more vigorous on drying.
Wash the Prints in cold water in order to extract all the Gallic Acid.
Then tone with _Sel d'or_ in the manner described in the next Section, and
fix in the usual way. The whites will with care be kept pure; or with only
a faint yellow tinge, which is not objectionable.
Upon comparing the developed Prints with others obtained by the direct
action of light upon the same sensitive paper, it is evident that the
advantage is _slightly_ on the side of the latter; but the difference is
so small that it would be overlooked in printing large subjects, for which
the Negative Process is more especially adapted. The _colour_ of both
kinds of Positives is the same, or perhaps a shade darker in the developed
proofs, which are usually of a violet-purple tone, but sometimes of a dark
chocolate-brown.
_A developing process with Serum of Milk._--The use of "whey" as a vehicle
for Chloride of Silver has something the same effect as that produced by
adding a Citrate. This may be traced to the presence of the Milk Sugar and
of a portion of uncoagulated Caseine left in the Serum.
The only difficulty in the process is to coagulate the milk in such a
way as to separate the greater part but not the whole of the Caseine.
Milk which has become sour, or to which an acid has been added, is not
considered so good for the purpose as that which has been treated with
rennet; and even when rennet is used it must be of the best quality or
its action will be imperfect. The serum must filter clear through,
blotting-paper; but it should not run very rapidly, or in all probability
the whole of the Caseine has been separated, and the fluid contains little
besides sugar. The whey which is left after cheese-making, commonly
answers the purpose, if clarified by beating it up with the white of
an egg and subsequently boiling and filtering. Globules of oil must be
separated as far as possible, or they will produce a greasiness of the
paper.[50]
[50] See the Vocabulary, Part III,, Art. "Milk," for further particulars.
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