A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Perfect cleanliness is essential. The salting or iodizing solution and
the Aceto-Nitrate Bath must be filtered clear, as the effect of small
suspended particles in producing spots is more seen when the image is
brought out by a developer.
It will be necessary to be far more careful in excluding white light
than in the ordinary process; and when Iodide of Silver is used, all the
precautions required in the case of Collodion Negatives must be taken.
Observe particularly that the dishes are kept clean, or the Gallo-Nitrate
of Silver will be rapidly discoloured (read the remarks at page 179).
Stereoscopic Negatives and small portraits are not successfully printed
by development; since it is difficult to obtain the most elaborate
definition, and there is a slight tendency to yellowness in the white
parts. Positives may be developed upon Albumen paper, but the Gallic Acid
is apt to discolour the lights.
In printing by development upon Chloride of Silver, the theory of the
subject must be particularly studied. When the weather is cold and the
light bad, the development of the image proceeds slowly, the Gallic Acid
Bath remains clear, and good half-tones are obtained; but under opposite
conditions, the developer may become turbid and the shadows be lost by
excessive deposit of Silver. This _over-development_ will be remedied by
printing the Negative in a more feeble light (near to the open window of
a room), and by adding Acetic Acid to the developer, about 5 or 10 minims
to the ounce, so as to bring out the image more slowly. The intensity of
action is thus lessened, and if the picture be not under-exposed, the
half-tones will be good.
Observe also when preparing papers with Citrate, that if too much
Carbonate of Soda be added in neutralizing the Citric Acid, Carbonate
of Silver will be deposited in the paper, the effect of which is to
remove by degrees the acidity of the Nitrate Bath, and to produce
over-development and excessive sensibility to light.
The colour of the proofs when taken from the Gallic Acid should be
_light red_; the gradation of tone not being usually so perfect when the
development is carried into the second or black stage.
It is not recommended to prepare too large a stock of the salted papers,
as they will probably be liable to mouldiness and decomposition unless
kept perfectly dry.
SECTION III.
_The Sel d'or Process for toning Positives._
This process is somewhat more troublesome than the plan of fixing and
toning in one solution, but possesses advantages which will presently be
enumerated. The description may be divided into the preparation of the
toning Bath, and the manipulatory details.
THE PREPARATION OF THE TONING BATH.
Take of
Chloride of Gold 1 grain.
Pure Hyposulphite of Soda 3 grains.
Hydrochloric Acid 4 minims.
Water, distilled or common 4 fluid ounces.
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