A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Illustration from the Non-metallic Elements._--If a stream of Chlorine
gas be passed into a solution containing the same salt as before
mentioned, viz. the Iodide of Potassium, the result is to liberate a
certain portion of Iodine, which dissolves in the liquid, and tinges it
of a brown colour. The element Chlorine, possessing a degree of chemical
energy superior to that of Iodine, prevails over it, and removes the
Potassium with which the Iodine was previously combined.
Chlorine + Iodide of Potassium
= Iodine + Chloride of Potassium.
_The same Law illustrated by the Metals._--A strip of Iron dipped in
solution of Nitrate of Silver becomes immediately coated with metallic
Silver; but a piece of Silver-foil may be left for any length of time in
Sulphate of Iron without undergoing change: the difference depends upon
the fact, that metallic Iron has a greater attraction for Oxygen than
Silver, and hence it displaces it from its solution.
Iron + Nitrate of Silver
= Silver + Nitrate of Iron.
_Illustrations amongst Binary Compounds._--If a few drops of solution
of Potash be added to solution of Nitrate of Silver, a brown deposit is
formed, which is the Oxide of Silver, sparingly soluble in water. That is
to say, as a stronger metal displaces _metallic Silver_, so does an oxide
of the same metal displace _Oxide of Silver_. Therefore bases like the
alkalies, alkaline earths, etc. cannot exist in a free state in solutions
of the salts of weaker bases,--a liquid containing Nitrate of Silver could
not also contain free Potash or Ammonia.
In the list given at page 306, the metallic elements are arranged
principally in the order of their chemical affinities; those of Potassium,
Sodium, Barium, etc. being the most marked.
As the alkalies displace the weaker bases from their combination with
acids, so the strong _acids_ displace weak acids from their combination
with bases. Thus, as
Oxide of Potassium + Acetate of Silver
= Oxide of Silver + Acetate of Potash;
So
Nitric Acid + Acetate of Silver
= Acetic Acid + Nitrate of Silver.
In the list of acids. Sulphuric Acid is usually placed first as being the
strongest, and Carbonic Acid, which is a gaseous substance, last. The
vegetable acids, such as Acetic, Tartaric, etc., are _intermediate_, being
weaker than the mineral acids, but stronger than Carbonic, or Hydrocyanic
Acid.
_The order of decompositions affected by the insolubility or the
volatility of the products which may be formed._--It might be inferred
from remarks already made, that on mixing saline solutions, a gradual
interchange of elements would take place, until the strongest acids
were associated with the strongest bases, and _vice versâ_. There are
many causes however which interfere to prevent this; one of which is
_volatility_.---
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