A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The violent effervescence which takes place on treating a _Carbonate_ of
any kind with an acid is due to the _gaseous_ nature of Carbonic Acid and
its escape in that form, which greatly facilitates the decomposition.
_Insolubility_ is also a cause which exercises a great influence on the
result which will follow in mixing solutions. If the formation of an
insoluble substance is possible by any interchange of elements, it will
take place. A solution of Chloride of Sodium added to Nitrate of Silver
invariably produces Chloride of Silver; the _insolubility_ of Chloride of
Silver being the cause which determines its formation.
So again, Sulphate of Lead and Protonitrate of Iron are produced by mixing
Nitrate of Lead with Sulphate of Iron; but if Nitrate of _Potash_ be
substituted for Nitrate of Lead, the result is uncertain, because there
are no elements present which can, by interchanging, form an insoluble
salt; Sulphate of Potash, although _sparingly_ soluble in water, not being
_insoluble_, like the Sulphate of Lead or the Sulphate of Baryta.
ON CHEMICAL NOMENCLATURE.
The nomenclature of the chemical _elements_ is mostly independent of any
rule; but an attempt has been made to obviate this in the case of those of
later discovery. Thus the names of the newly-found _metals_ usually end
in _um_, as Potassium, Sodium, Barium, Calcium, etc.; and those elements
which possess analogous characters have corresponding terminations
assigned to them, as Chlorine, Bromine, Iodine, Fluorine, etc.
_Nomenclature of Binary Compounds._--These are often named by attaching
the termination _ide_ to the more important element of the two; as, the
Ox_ide_ of Hydrogen, or Water; the Chlor_ide_ of Silver; the Sulph_ide_
of Silver. Binary compounds of Sulphur however are sometimes termed
Sulphurets, as the _Sulphuret_ or the _Sulphide_ of Silver indifferently.
When the same body combines with Oxygen, or the corresponding element, in
more than one proportion, the prefix _proto_ is applied to that containing
the least Oxygen; _sesqui_ to that with once and a half as much as the
_proto_; _bi_ or _bin_ to that with twice as much; and _per_ to the one
containing the most Oxygen of all. As examples, take the following:--The
Protoxide of Iron; the Sesquioxide of Iron: the Protochloride of Mercury;
the Bichloride of Mercury. In these examples the Sesquioxide of Iron
is also a _Per_oxide, because no higher simple oxide is known, and the
Bichloride of Mercury is a _Per_chloride for a similar reason.
When an inferior compound is discovered, it is often termed _sub_; as the
Suboxide of Silver, the Subchloride of Silver. These bodies contain the
least known quantity of Oxygen and Chlorine respectively, and are hence
entitled to the prefix _proto_; but being of minor importance, they are
excepted from the general rule.
The combinations of metallic elements with each other are termed "alloys;"
or if containing Mercury, "amalgams."
Public-domain text, read in full here on John Shaqi.
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