A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Therefore it appears that 8 grains of Oxygen are _equivalent_ to 36 grains
of Chlorine and to 126 grains of Iodine, seeing that these quantities all
play the same part in combining; and so it is with regard to the other
elements,--to every one of them a figure can be assigned which represents
the number of parts by weight in which that element unites with others.
These figures are the "equivalents" or "combining proportions," and they
are denoted by the _symbol_ of the element. A symbol does not stand as
a simple representative of an element, but as a representative of _one
equivalent_ of an element. Thus "O" indicates 8 parts by weight of Oxygen;
"Cl" one equivalent, or 36 parts by weight, of Chlorine; and so with the
rest.
Observe however that these figures, termed "equivalents," do not refer
to the _actual number_ of parts by weight, but only to the _ratio_ which
exists between them: if Oxygen is 8, then Chlorine is 36; but if we term
Oxygen 100, as some have proposed, then Chlorine would be 442·65.
In the scale of equivalents now usually adopted, Hydrogen, as being the
lowest of all, is taken as unity, and the others are related to it.
_Equivalents of Compounds._--The law of equivalent proportions applies
to compounds as well as to simple bodies, the combining proportion of a
compound being always the sum of the equivalents of its constituents. Thus
Sulphur is 16, and Oxygen 8, therefore Sulphuric Acid, or SO{3}, equals
40. The equivalent of Nitrogen is 14, that of Nitric Acid, or NO{5}, is 54.
The same rule applies with regard to salts. Take for instance the Nitrate
of Silver: it contains
Equivalent.
Nitrogen 14
6 Oxygen 48
Silver 108
---
Total of equivalents, or equivalent } 170
of the Nitrate of Silver }
_Practical application of the Laws of Combination ._--The utility of being
acquainted with the law of combining proportions is obvious when their
nature is understood. As bodies both unite with and replace each other
in equivalents, a simple calculation shows at once how much of each
element or compound will be required in a given reaction. Thus, supposing
it be desired to convert 100 grains of Nitrate of Silver into _Chloride_
of Silver, the weight of Chloride of Sodium which will be necessary is
deduced thus:--one equivalent, or 170 parts, of Nitrate of Silver, is
decomposed by an equivalent, or 60 parts, of Chloride of Sodium. Therefore
as 170 : 60 :: 100 : 35·2;
that is, 35·2 grains of Salt will precipitate, in the state of Chloride,
the whole of the Silver contained in 100 grains of Nitrate.
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