A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
So again, in order to form the Iodide of Silver, the proportions in which
the two salts should be mixed is thus shown. The equivalent of Iodide of
Potassium is 166, and that of Nitrate of Silver is 170. These numbers so
nearly correspond, that it is common to direct that equal weights of the
two salts should be taken.
One more illustration will suffice. Supposing it be required to form 20
grains of Iodide of Silver--how much Iodide of Potassium and Nitrate of
Silver must be used? One equivalent, or 166 parts, of Iodide of Potassium,
will yield an equivalent, or 234 parts, of Iodide of Silver; therefore
as 234 : 166 :: 20 : 14·2.
Hence, if 14·2 grains of the Iodide of Potassium be dissolved in water,
and an equivalent quantity, viz. 14·5 grains, of the Nitrate of Silver
added, the yellow precipitate, when washed and dried, will weigh precisely
20 grains.
ON THE ATOMIC THEORY.
The atomic theory, originally proposed by Dalton, so much facilitates the
comprehension of chemical reactions generally, that it may be useful to
give a short sketch of it.
It is supposed that all matter is made up of an infinite number of minute
atoms, which are elementary, and do not admit of further division. Each
of these atoms possesses an actual weight, although inappreciable by our
present methods of investigation. Simple atoms, by uniting with each
other, form _compound atoms_; and when these compounds are broken up, the
elementary constituent atoms are not destroyed, but separate from each
other, in possession of all their original properties.
In representing the simple atomic structure of bodies, _circles_ may be
used, as in the following diagram.
[Illustration: Fig. 1. Fig. 2. Fig. 3.]
Fig. 1 is a compound atom of Sulphuric Acid, consisting of an atom of
Sulphur united intimately with three of Oxygen; fig. 2 is an atom of
Peroxide of Nitrogen, NO{4}; and fig. 3, an atom of Nitric Acid, composed
of Nitrogen 1 atom. Oxygen 5 atoms, or in symbols NO{5}.
_The term "atomic weight" substituted for equivalent proportion._--If
we suppose that the simple atoms of different kinds of matter _differ
in weight_, and that this difference is expressed by their equivalent
numbers, the whole laws of combination follow by the simplest reasoning.
It is easy to understand that an atom of one element, or compound, would
displace, or be substituted for, a single atom of another; therefore,
taking as the illustration the decomposition of Iodide of Potassium by
Chlorine,--the weight of the latter element required to liberate 126
grains of Iodine is 36 grains, because _the weights of the atoms of those
two elementary bodies are as 36 to 126_. So again, in the reaction
between Chloride of Sodium and Nitrate of Silver, a compound atom of the
former, represented by the weight 60, reacts upon a compound atom of the
latter, which equals 170.
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