A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Inorganic bodies, as already shown, unite _in pairs_,--two elements join
to form a binary compound; two binary compounds produce a salt; two salts
associated together form a double salt. With organic bodies however the
arrangement is different,--the elementary atoms are all grouped equally
in one compound atom, which is highly complex in structure, and cannot be
split up into binary products.
Observe also, as characteristic of Organic Chemistry, the apparent
similarity in composition between bodies which differ widely in
properties. As examples take _Lignine_, or cotton fibre, and Starch,--each
of which contains the three elements united as C{24}H{20}O{20}.
_Mode of distinguishing between Organic and Inorganic matter._--A simple
means of doing this is as follows:-- place the suspected substance upon
a piece of Platinum-foil, and heat it to redness with a spirit-lamp: if
it first _blackens_, and then burns completely away, it is probably of
organic origin. This test depends upon the fact, that the constituent
elements of organic bodies are all either themselves volatile, or capable
of forming volatile combinations with Oxygen. Inorganic substances, on the
other hand, are often unaffected by heat, or, if volatile, are dissipated
without previous charring.
The action of heat upon organic matter may further be illustrated by the
combustion of coal or wood in an ordinary furnace;--first, an escape
of Carbon and Hydrogen, united in the form of volatile gaseous matter,
takes place, leaving behind a black cinder, which consists of Carbon and
inorganic matter combined; afterwards this Carbon burns away into Carbonic
Acid, and a grey ash is left which is composed of inorganic salts, and is
indestructible by heat.
CHAPTER II.
VOCABULARY OF PHOTOGRAPHIC CHEMICALS.
ACETIC ACID.
Symbol, C{4}H{3}O{3} + HO. Atomic weight, 60.
Acetic Acid is a product of the _oxidation_ of Alcohol. Spirituous
liquids, when perfectly pure, are not affected by exposure to air; but if
a portion of yeast, or Nitrogenous organic matter of any kind, be added,
it soon acts as a _ferment_, and causes the spirit to unite with oxygen
derived from the atmosphere, and so to become sour from formation of
Acetic Acid, or "vinegar."
Acetic Acid is also produced on a large scale by heating _wood_ in close
vessels: a substance distils over which is Acetic Acid contaminated with
empyreumatic and tarry matter; it is termed Pyroligneous Acid, and is much
used in commerce.
The most concentrated Acetic Acid may be obtained by neutralizing common
vinegar with Carbonate of Soda, and crystallizing out the Acetate of Soda
so formed; this Acetate of Soda is then distilled with Sulphuric Acid,
which removes the Soda and liberates Acetic Acid: the Acetic Acid being
volatile, distils over, and may be condensed.
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