A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Properties of Acetic Acid._--The strongest acid contains only a single
atom of water; it is sold under the name of "Glacial Acetic Acid," so
called from its property of solidifying at a moderately low temperature.
At about 50° the crystals melt, and form a limpid liquid of pungent odour
and a density nearly corresponding to that of water; the specific gravity
of Acetic Acid however is no test of its real strength, which can only be
estimated by analysis.
The commercial _Glacial_ Acetic Acid is often diluted with water, which
may be suspected if it does not solidify during the cold winter months.
Sulphurous and Hydrochloric Acids are also common impurities. They are
injurious in Photographic Processes, from their property of precipitating
Nitrate of Silver. To detect them proceed as follows:--dissolve a small
crystal of Nitrate of Silver in a few drops of water, and add to it about
half a drachm of the Glacial Acid; the mixture should remain quite clear
even when exposed to the light. Hydrochloric and Sulphurous Acid produce
a white deposit of Chloride or Sulphite of Silver; and if _Aldehyde_ or
volatile tarry matter be present in the Acetic Acid, the mixture with
Nitrate of Silver, although clear at first, becomes discoloured by the
action of light.
Glacial Acetic Acid sometimes has a smell of garlic. In this state it
probably contains an organic Sulphur Acid, and is unfit for use.
Many employ a cheaper form of Acetic Acid, sold by druggists as
"Beaufoy's" acid; it should be of the strength of the Acetic Acid fortiss.
of the London Pharmacopœia, containing 30 per cent, real acid. It will be
advisable to test it for Sulphuric Acid (see Sulphuric Acid), and other
impurities, before use.
ACETATE OF SILVER. _See_ Silver, Acetate of.
ALBUMEN.
Albumen is an organic principle found both in the animal and vegetable
kingdom. Its properties are best studied in the _white of egg_, which is
a very pure form of Albumen.
Albumen is capable of existing in two states; in one of which it is
soluble, in the other insoluble, in water. The aqueous solution of the
soluble variety gives a slightly alkaline reaction to test-paper; it is
somewhat thick and glutinous, but becomes more fluid on the addition of a
small quantity of an alkali, such as Potash or Ammonia.
Soluble Albumen may be converted into the _insoluble_ form in the
following ways:--
1. _By the application of heat._--A moderately strong solution of
Albumen becomes opalescent and coagulates on being heated to about 150°
Fahrenheit, but a temperature of 212° is required if the liquid is very
dilute. A layer of _dried_ Albumen cannot easily be coagulated by the mere
application of heat.
2. _By addition of strong acids._--Nitric Acid coagulates Albumen
perfectly without the aid of heat. Acetic Acid however acts differently,
appearing to enter into combination with the Albumen, and forming a
compound soluble in warm water acidified by Acetic Acid.
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