A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
3. _By the action of metallic salts._--Many of the salts of the metals
coagulate Albumen completely. Nitrate of Silver does so; also the
Bichloride of Mercury. Ammoniacal Oxide of Silver however does not
coagulate Albumen.
The white precipitate formed on mixing Albumen with Nitrate of Silver
is a chemical compound of the animal matter with Protoxide of Silver.
This substance, which has been termed Albuminate of Silver, is soluble
in Ammonia and Hyposulphite of Soda; but after exposure to light, or
heating in a current of Hydrogen gas, it assumes a brick-red colour, being
probably reduced to the condition of an organic compound of a _Suboxide_
of Silver. It is then almost insoluble in Ammonia, but enough dissolves
to tinge the liquid wine-red. The _red coloration_ of solution of Nitrate
of Silver employed in sensitizing the Albuminized photographic paper is
probably produced by the same compound, although, often referred to the
presence of Sulphuret of Silver.
Albumen also combines with Lime and Baryta. When Chloride of Barium is
used with Albumen, a white precipitate of this kind usually forms.
_Chemical composition of Albumen._--Albumen belongs to the _Nitrogenous_
class of organic substances (see page 325). It also contains small
quantities of Sulphur and Phosphorus.
ALCOHOL.
Symbol, C{4}H{6}O{2}. Atomic weight, 46.
Alcohol is obtained by the careful distillation of any spirituous or
fermented liquor. If wine or beer be placed in a retort, and heat applied,
the Alcohol, being more volatile than water, rises first, and is condensed
in an appropriate receiver; a portion of the vapour of water however
passes over with the Alcohol, and dilutes it to a certain extent, forming
what is termed "Spirits of Wine." Much of this water may be removed by
redistillation from Carbonate of Potash, in the manner described at
page 196 of this work; but in order to render the Alcohol thoroughly
_anhydrous_, it is necessary to employ _Quicklime_, which possesses a
still greater attraction for water. An equal weight of this powdered lime
is mixed with strong Alcohol of ·823, and the two are distilled together.
_Properties of Alcohol._--Pure anhydrous Alcohol is a limpid liquid, of an
agreeable odour and pungent taste; sp. gr. at 60°, ·794. It absorbs vapour
of water, and becomes diluted by exposure to damp air; boils at 173° Fahr.
It has never been frozen.
Alcohol distilled from Carbonate of Potash has a specific gravity of ·815
to ·823, and contains 90 to 93 per cent, of real spirit.
The specific gravity of ordinary rectified Spirits of Wine is usually
about ·840, and it contains 80 to 83 per cent, of absolute Alcohol.
AMMONIA.
Symbol, NH{3} or NH{4}O. Atomic weight, 17.
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