A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Chlorine is more powerful in its affinities than either Bromine or
Iodine. The salts formed by these three elements are closely analogous
in composition and often in properties. Those of the Alkalies, Alkaline
Earths, and many of the Metals, are soluble in water; but the Silver salts
are insoluble; the Lead salts sparingly so.
The combinations of Chlorine, Bromine, Iodine, and Fluorine, with
Hydrogen, are acids, and neutralize Alkalies in the usual, manner, with
formation of Alkaline Chloride and water (see page 311).
The test by which the presence of Chlorine is detected, either free or in
combination with bases, is _Nitrate of Silver_; it gives a white curdy
precipitate of Chloride of Silver, insoluble in Nitric Acid, but soluble
in Ammonia. The solution of Nitrate of Silver employed as the test must
not contain Iodide of Silver, as this compound is precipitated by dilution.
CHLORIDE OF AMMONIUM.
Symbol, NH{4}Cl. Atomic weight, 54.
This salt, also known as Muriate or Hydrochlorate of Ammonia, occurs in
commerce in the form of colourless and translucent masses, which are
procured by _sublimation_, the dry salt being volatile when strongly
heated. It dissolves in an equal weight of boiling, or in three parts of
cold water. It contains more Chlorine in proportion to the weight used
than Chloride of Sodium, the atomic weights of the two being as 54 to 60.
CHLORIDE OF BARIUM.
Symbol, BaCl + 2 HO. Atomic weight, 123.
Barium is a metallic element very closely allied to Calcium, the
elementary basis of Lime. The Chloride of Barium is commonly employed as
a test for Sulphuric Acid, with which it forms an insoluble precipitate
of Sulphate of Baryta. It is also said to affect the colour of the
Photographic image when used in preparing Positive paper, which may
possibly be due to a chemical combination of Baryta with Albumen; but
it must be remembered that this Chloride, from its high atomic weight,
contains less Chlorine than the alkaline Chlorides (see page 124).
_Properties of Chloride of Barium._--Chloride of Barium occurs in the
form of white crystals, soluble in about two parts of water, at common
temperature. These crystals contain two atoms of water of crystallization,
which are expelled at 212°, leaving the anhydrous Chloride.
CHLORIDE OF GOLD. See Gold, Chloride of.
CHLORIDE OF SODIUM.
Symbol, NaCl. Atomic weight, 60.
Common Salt exists abundantly in nature, both in the form of solid
rock-salt and dissolved in the waters of the ocean.
Properties of the pure Salt.--Fusible without decomposition at low
redness, but sublimes at higher temperatures; the melted salt concretes
into a hard white mass on cooling. Nearly insoluble in absolute alcohol,
but dissolves in minute quantity in rectified spirit. Soluble in three
parts of water, both hot and cold. Crystallizes in cubes, which are
anhydrous.
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