A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Impurities of Common Salt._--Table Salt often contains large quantities
of the Chlorides of Magnesium and Calcium, which, being deliquescent,
produce a dampness by absorption of atmospheric moisture: Sulphate of
Soda is also commonly present. The salt may be purified by repeated
re-crystallization, but it is more simple to prepare the pure compound
_directly_, by neutralizing Hydrochloric Acid with Carbonate of Soda.
CHLORIDE OF SILVER. _See_ Silver, Chloride of.
CITRIC ACID.
This acid is found abundantly in lemon-juice and in lime-juice. It occurs
in commerce in the form of large crystals, which are soluble in less than
their own weight of water at 60°.
Commercial Citric Acid is sometimes mixed with Tartaric Acid. The
adulteration may be discovered by making a concentrated solution of the
acid and adding _Acetate of Potash_; crystals of Bitartrate of Potash will
separate if Tartaric Acid be present.
Citric Acid is tribasic. It forms with Silver a white insoluble salt,
containing 3 atoms of Oxide of Silver to 1 atom of Citric Acid. When the
Citrate of Silver is heated in a current of Hydrogen gas, a part of the
acid is liberated and the salt is reduced to a Citrate of Suboxide of
Silver; which is of a red colour. The action of white light in reddening
Citrate of Silver is shown by the Author to be of a similar nature.
CYANIDE OF POTASSIUM.
Symbol, KC{2}N, or KCy. Atomic weight, 66.
This salt is a compound of Cyanogen gas with the metal Potassium.
Cyanogen is not an elementary body, like Chlorine or Iodine, but consists
of Carbon and Nitrogen united in a peculiar manner. Although a compound
substance, it reacts in the manner of an element, and is therefore
(like Ammonium, previously described) an exception to the usual laws of
chemistry. Many other bodies of a similar character are known.
Properties of Cyanide of Potassium.--These have been sufficiently
described at page 44, to which the reader is referred.
ETHER.
Symbol, C{4}H{5}O. Atomic weight, 37.
Ether is obtained by distilling a mixture of Sulphuric Acid and Alcohol.
If the formula of Alcohol (C{4}H{6}O{2}) be compared with that of Ether,
it will be seen to differ from it in the possession of an additional atom
of Hydrogen and of Oxygen: in the reaction the Sulphuric Acid removes
these elements in the form of water, and by so doing converts one atom
of Alcohol into an atom of Ether. The term Sulphuric applied to the
commercial Ether has reference only to the manner of its formation.
Properties of Ether.--The properties of Ether have been described to some
extent at pages 85 and 195. The following particulars however may be
added. It is neither acid nor alkaline to test-paper. Specific gravity, at
60°, about ·720. Boils at 98° Fahrenheit. The vapour is exceedingly dense,
and may be seen passing off from the liquid and falling to the ground:
hence the danger of pouring Ether from one bottle to another if a flame be
near at hand.
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