A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
This is an organic substance somewhat analogous to Albumen, but differing
from it in properties. It is obtained by subjecting bones, hoofs, horns,
calves' feet, etc., to the action of boiling water. The jelly formed
on cooling is termed size, or, when dried and cut into slices, _glue_.
Gelatine, as it is sold in the shops, is a pure form of Glue. _Isinglass_
is gelatine prepared, chiefly in Russia, from the air-bladders of certain
species of sturgeon.
_Properties of Gelatine._--Gelatine softens and swells up in cold water,
but does not _dissolve_ until heated: the hot solution, on cooling, forms
a tremulous jelly. One ounce of cold water will retain about three grains
of Isinglass without gelatinizing; but much depends upon the temperature,
a few degrees greatly affecting the result.
When long boiled in water, and especially in presence of an acid, such
as the Sulphuric, Gelatine undergoes a peculiar modification, and the
Solution loses either partially or entirely its property of solidifying to
a jelly.
GLYCERINE.
Fatty bodies are resolved by treatment with an alkali into an Acid--which
combines with the alkali, forming a _soap_,--and Glycerine, remaining in
solution.
Pure Glycerine, as obtained by Price's patent process of distillation,
is a viscid liquid of sp. gr. about 1·23; miscible in all proportions
with water and Alcohol. It is peculiarly a neutral substance, exhibiting
no tendency to combine with acids or bases. It has little or no action
upon Nitrate of Silver in the dark, and reduces it very slowly even when
exposed to light.
GLYCYRRHIZINE.
Glycyrrhizine, obtained from the fresh root of Liquorice, is a substance
intermediate in properties between a sugar and a resin. Sparingly soluble
in water but very soluble in Alcohol. It precipitates strong solution of
Nitrate of Silver white, but the deposit becomes reddened by exposure
to light. Its preparation is described in the larger works on organic
chemistry.
GOLD, CHLORIDE OF.
Symbol, AuCl{3}. Atomic weight, 303.
This salt is formed by dissolving pure metallic Gold in Nitro-hydrochloric
Acid, and evaporating at a gentle heat. The solution affords deliquescent
crystals of a deep orange colour.
Chloride of Gold, in a state fit for Photographic use, may easily be
obtained by the following process:--Place a half-sovereign in any
convenient vessel, and pour on it half a drachm of Nitric Acid mixed with
two and a half drachms of Hydrochloric Acid and three drachms of water;
digest by a gentle heat, but do not _boil_ the acid, or much of the
Chlorine will be driven off in the form of gas. At the expiration of a few
hours add fresh Aqua-Regia in quantity the same as at first, which will
probably complete the solution, but if not, repeat the process a third
time.
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