A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Lastly, neutralize the liquid by adding Carbonate of Soda until all
effervescence ceases, and a green precipitate forms; this is _Carbonate
of Copper_, which must be allowed several hours to separate thoroughly.
The Chloride of Gold is thus freed from Copper and Silver, with which the
metallic Gold is alloyed in the standard coin of the realm. The solution
so prepared will be _alkaline_, and consequently prone to a reduction
of metallic Gold: a slight extra quantity of Hydrochloric acid should
therefore be added, sufficient to redden a piece of immersed litmus-paper.
The weight of a half-sovereign is about 61 grains, of which 56 grains are
pure Gold. This is equivalent to 86 grains of Chloride of Gold, which will
be the quantity contained in the solution.
The following process for preparing Chloride of Gold is more perfect than
the last:--Dissolve the Gold coin in Aqua-Regia as before; then boil with
excess of Hydrochloric Acid, to destroy the Nitric Acid,--dilute largely
with distilled water, and add a filtered aqueous solution of common
Sulphate of Iron (6 parts to 1 of Gold); collect the precipitated Gold,
which is now free from copper; redissolve in Aqua-Regia, and evaporate to
dryness on a water bath.
Avoid using _Ammonia_ to neutralize Chloride of Gold, as it would occasion
a deposit of "Fulminating Gold," the properties of which are described in
the next page.
_Properties of Chloride of Gold._--As sold in commerce it usually contains
excess of Hydrochloric Acid, and is then of a bright yellow colour; but
when neutral and somewhat concentrated, it is dark red (_Leo ruber_ of the
alchemists). It gives no precipitate with Carbonate of Soda unless heat
be applied; the free Hydrochloric Acid present forms, with the alkali.
Chloride of Sodium, which unites with the Chloride of Gold, and produces
a double salt, Chloride of Gold and Sodium, soluble in water.
Chloride of Gold is decomposed with precipitation of metallic Gold by
Charcoal, Sulphurous Acid, and many of the vegetable acids; also by
Protosulphate and Protonitrate of Iron. It tinges the cuticle of an
indelible purple tint. It is soluble in Alcohol and in Ether.
GOLD, FULMINATING.
This is a yellowish-brown substance, precipitated on adding Ammonia to a
strong solution of Chloride of Gold.
It may be dried carefully at 212°, but explodes violently on being heated
suddenly to about 290°. Friction also causes it to explode when dry; but
the moist powder may be rubbed or handled without danger. It is decomposed
by Sulphuretted Hydrogen.
Fulminating Gold is probably an Aurate of Ammonia, containing 2 atoms of
Ammonia to 1 atom of Peroxide of Gold.
GOLD, HYPOSULPHITE OF.
Symbol, AuO S{2}O{2}. Atomic weight, 253.
Hyposulphite of Gold is produced by the reaction of Chloride of Gold upon
Hyposulphite of Soda (see page 133).
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