A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The liquid known by this name, and formed on passing Sulphuretted Hydrogen
gas into Ammonia, is a double Sulphuret of Hydrogen and Ammonium. In the
preparation, the passage of the gas is to be continued until the solution
gives no precipitate with Sulphate of Magnesia, and smells strongly of
Hydrosulphuric Acid.
_Properties._--Colourless at first, but afterwards changes to yellow,
from liberation and subsequent solution of Sulphur. Becomes milky on the
addition of any acid. Precipitates, in the form of Sulphuret, all the
metals which are affected by Sulphuretted Hydrogen, and, in addition,
those of the class to which Iron, Zinc, and Manganese belong.
Hydrosulphate of Ammonia is employed in Photography to darken the Negative
image, and also in the preparation of Iodide of Ammonium, the separation
of Silver from Hyposulphite solutions, etc.
HYPOSULPHITE OF SODA.
Symbol, NaO S{2}O{2} + 5 HO. Atomic weight, 125.
The chemistry of Hyposulphurous Acid and the Hyposulphite of Soda has been
sufficiently described at pages 43, 129, and 137 of the present Work. The
crystallized salt includes five atoms of water of crystallization.
HYPOSULPHITE OF GOLD. _See_ Gold, Hyposulphite of.
HYPOSULPHITE OF SILVER. _See_ Silver, Hyposulphite of.
ICELAND MOSS.
_Cetraria Islandica._--A species of Lichen found in Iceland and the
mountainous parts of Europe; when boiled in water, it first swells up, and
then yields a substance which gelatinizes on cooling.
It contains Lichen Starch, a bitter principle soluble in Alcohol, termed
"Cetrarine," and common Starch; traces of Gallic Acid and Bitartrate of
Potash are also present.
IODINE.
Symbol, I. Atomic weight, 126.
Iodine is chiefly prepared at Glasgow, from _kelp_, which is the fused
ash obtained on burning seaweeds. The waters of the ocean contain minute
quantities of the Iodides of Sodium and Magnesium, which are separated and
stored up by the growing tissues of the marine plant.
In the preparation, the mother-liquor of kelp is evaporated to dryness
and distilled with Sulphuric Acid; the Hydriodic Acid first liberated is
decomposed by the high temperature, and fumes of Iodine condense in the
form of opaque crystals.
_Properties._--Iodine has a bluish-black colour and metallic lustre; it
stains the skin yellow, and has a pungent smell, like diluted Chlorine.
It is extremely volatile when moist, boils at 350°, and produces dense
violet-coloured fumes, which condense in brilliant plates. Specific
gravity 4·946. Iodine is very sparingly soluble in water, 1 part requiring
7000 parts for perfect solution; even this minute quantity however
tinges the liquid of a brown colour. Alcohol and Ether dissolve it more
abundantly, forming dark-brown solutions. Iodine also dissolves freely in
solutions of the alkaline Iodides, such as the Iodide of Potassium, of
Sodium, and of Ammonium.
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