A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Hydrochloric Acid is a volatile gas, which may be liberated from most of
the salts termed Chlorides by the action of Sulphuric Acid. The acid, by
its superior affinities, removes the base; thus,--
NaCl + HO SO{3} = NaO SO{3} + HCl.
Properties.--Abundantly soluble in water, forming the liquid Hydrochloric
or Muriatic Acid of commerce. The most concentrated solution of
Hydrochloric Acid has a sp. gr. 1·2, and contains about 40 per cent, of
gas; that commonly sold is somewhat weaker, sp. gr. 1·14 = 28 per cent,
real acid.
Pure Hydrochloric Acid is colourless, and fumes in the air. The yellow
colour of the commercial acid depends upon the presence of traces of
Perchloride of Iron, or of organic matter; commercial Muriatic Acid also
often contains a portion of free Chlorine and of Sulphuric Acid.
HYDRIODIC ACID.
Symbol, HI. Atomic weight, 127.
This is a gaseous compound of Hydrogen and Iodine, corresponding in
composition to the Hydrochloric Acid. It cannot however, from its
instability, be obtained in the same manner, since, on distilling
an Iodide with Sulphuric Acid, the Hydriodic Acid first formed is
subsequently decomposed into Iodine and Hydrogen. An aqueous solution of
Hydriodic Acid is easily prepared by adding Iodine to water containing
Sulphuretted Hydrogen gas; a decomposition takes place, and Sulphur is set
free: thus, HS + I = HI + s.
Properties.--Hydriodic Acid is very soluble in water, yielding a strongly
acid liquid. The solution, colourless at first, soon becomes brown from
decomposition, and liberation of free Iodine. It may be restored to its
original condition by adding solution of Sulphuretted Hydrogen.
HYDROSULPHURIC ACID.
Symbol, HS. Atomic weight, 17.
This substance, also known as Sulphuretted Hydrogen, is a gaseous compound
of Sulphur and Hydrogen, analogous in composition to the Hydrochloric and
Hydriodic Acid. It is usually prepared by the action of dilute Sulphuric
Acid upon Sulphuret of Iron, as described at page 373; the decomposition
being similar to that involved in the preparation of the Hydrogen acids
generally:--
FeS + HO SO{3} = FeO SO{3} + HS.
Properties.--Cold water absorbs three times its bulk of Hydrosulphuric
Acid, and acquires the peculiar putrid odour and poisonous qualities
of the gas. The solution is faintly acid to test-paper, and becomes
opalescent on keeping, from gradual separation of Sulphur. It is
decomposed by Nitric Acid, and also by Chlorine and Iodine. It
precipitates Silver from its solutions in the form of black Sulphuret
of Silver; also Copper, Mercury, Lead, etc.; but Iron and other metals
of that class are not affected, if the liquid contains free acid.
Hydrosulphuric Acid is constantly employed in the chemical laboratory for
these and other purposes.
HYDROSULPHATE OF AMMONIA.
Symbol, NH{4}S HS. Atomic weight, 51.
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