A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The impurities of commercial Iodide of Potassium, with the means to be
adopted for their removal, are fully given at page 197.
IODIDE OF SILVER. _See_ Silver, Iodide of.
IODOFORM.
The composition of this substance is analogous to that of Chloroform,
Iodine being substituted for Chlorine. It is obtained on boiling together
Iodine, Carbonate of Potash, and Alcohol.
Iodoform occurs in yellow nacrous crystals, which have a saffron-like
odour. It is insoluble in water, but soluble in spirit.
IRON, PROTOSULPHATE OF.
Symbol, FeO SO{3} + 7 HO. Atomic weight, 139.
The properties of this salt, and of the two salifiable Oxides of Iron, are
described at page 29. It dissolves in rather more than an equal weight of
cold water, or in less of boiling water.
Aqueous solution of Sulphate of Iron absorbs the Binoxide of Nitrogen,
acquiring a deep olive-brown colour: as this gaseous Binoxide is itself a
reducing agent, the liquid so formed has been proposed as a more energetic
developer than the Sulphate of Iron alone (?).
IRON, PROTONITRATE OF.
Symbol, FeO NO{3} + 7 HO. Atomic weight, 153.
This salt, by careful evaporation _in vacuo_ over Sulphuric Acid, forms
transparent crystals, of a light green colour, and containing 7 atoms
of water, like the Protosulphate. It is exceedingly unstable, and soon
becomes red from decomposition, unless preserved from contact with air.
The preparation of solution of Protonitrate of Iron for developing
Collodion Positives, is given at page 206.
IRON, PERCHLORIDE OF.
Symbol, Fe{2}Cl{3}. Atomic weight, 164.
There are two Chlorides of Iron, corresponding in composition to the
Protoxide and the Sesquioxide respectively. The Protochloride is very
soluble in water, forming a green solution, which precipitates a dirty
white Protoxide on the addition of an alkali. The Perchloride, on the
other hand, is dark brown, and gives a foxy-red precipitate with alkalies.
_Properties._--Perchloride of Iron may be obtained in the solid form by
heating Iron wire in excess of Chlorine; it condenses in the shape of
brilliant and iridescent brown crystals, which are volatile, and dissolve
in water, the solution being acid to test-paper. It is also soluble in
Alcohol, forming the Tinctura Ferri Sesquichloridi of the Pharmacopœia.
Commercial Perchloride of Iron ordinarily contains an excess of
Hydrochloric Acid.
LITMUS.
Litmus is a vegetable substance prepared from various _lichens_, which are
principally collected on rocks adjoining the sea. The colouring matter is
extracted by a peculiar process, and afterwards made up into a paste with
chalk, plaster of Paris, etc.
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