A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Litmus occurs in commerce in the form of small cubes of a fine violet
colour. In using it for the preparation of test-papers, it is digested
in hot water, and sheets of porous paper are soaked in the blue liquid
so formed. The red papers are prepared at first in the same manner, but
afterwards placed in water which has been rendered faintly acid with
Sulphuric or Hydrochloric Acid.
MERCURY, BICHLORIDE OF.
Symbol, HgCl{2}. Atomic weight, 274.
This salt, also called Corrosive Sublimate, and sometimes _Chloride of
Mercury_ (the atomic weight of Mercury being halved), may be formed by
heating Mercury in excess of Chlorine, or more economically, by subliming
a mixture of Persulphate of Mercury and Chloride of Sodium.
_Properties._--A very corrosive and poisonous salt, usually sold in
semi-transparent, crystalline masses, or in the state of powder. Soluble
in 16 parts of cold, and in 3 of hot water; more abundantly so in Alcohol,
and also in Ether. The solubility in water may be increased by the
addition of free Hydrochloric Acid, or of Chloride of Ammonium.
The Protochloride of Mercury is an insoluble white powder, commonly known
under the name of _Calomel_.
METHYLIC ALCOHOL.
This liquid, known also by the names of _wood naphtha_ and _pyroxylic
spirit_, is one of the volatile products of the destructive distillation
of wood. It is very volatile and limpid, with a pungent odour.
By a recent excise regulation, ordinary Spirit mixed with ten per cent, of
wood naphtha is sold free of duty, under the name of "Methylated Spirit."
MILK.
The Milk of herbivorous animals contains three principal
constituents--Fatty matter, Caseine, and Sugar; in addition to these,
small quantities of the Chloride of Potassium, and of Phosphates of Lime
and Magnesia, are present.
The fatty matter is contained in small cells, and forms the greater part
of the cream which rises to the surface of the milk on standing; hence
shimmed milk is to be preferred for Photographic use.
The second constituent, Caseine, is an organic principle somewhat
analogous to Albumen in composition and properties. Its aqueous solution
however does not, like Albumen, _coagulate_ on boiling, unless _an acid_
be present, which probably removes a small portion of alkali with which
the Caseine was previously combined. The substance termed "rennet," which
is the dried stomach of the calf, possesses the property of coagulating
Caseine, but the exact mode of its action is unknown. Sherry-wine is also
commonly employed to curdle Milk; but brandy and other spirituous liquids,
when free from acid and astringent matter, have no effect.
In all these cases a portion of the Caseine usually remains in a soluble
form in the _whey_; but when the Milk is coagulated by the addition of
acids, the quantity so left is very small, and hence the use of the
rennet is to be preferred, since the presence of Caseine facilitates the
reduction of the sensitive Silver salts.
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