A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
_Impurities of Commercial Nitric Acid._--These are principally Chlorine
and Sulphuric Acid; also Peroxide of Nitrogen, which tinges the acid
yellow, as already described. Chlorine is detected by diluting the acid
with an equal bulk of distilled water, and adding a few drops of Nitrate
of Silver,--a _milkiness_, which, is Chloride of Silver in suspension,
indicates the presence of Chlorine. In testing for Sulphuric Acid, dilute
the Nitric Acid as before, and drop in _a single drop_ of solution of
Chloride of Barium; if Sulphuric Acid be present, an insoluble precipitate
of Sulphate of Baryta will be formed.
NITROUS ACID. _See_ Silver, Nitrite of.
NITRATE OF POTASH.
Symbol, KO NO{5}. Atomic weight, 102.
This salt, also termed _Nitre_, or _Saltpetre_, is an abundant natural
product, found effloresced upon the soil in certain parts of the East
Indies. It is also produced artificially in what are called Nitre-beds.
The properties of Nitrate of Potash are described as far as necessary at
page 190.
NITRATE OF BARYTA.
Symbol, BaO NO{5}. Atomic weight, 131.
Nitrate of Baryta forms octahedral crystals, which are anhydrous. It is
considerably less soluble than the Chloride of Barium, requiring 12 parts
of cold and 4 of boiling water for solution. It may be substituted for the
Nitrate of Lead in the preparation of Protonitrate of Iron.
NITRATE OF LEAD.
Symbol, PbO NO{5}. Atomic weight, 166.
Nitrate of Lead is obtained by dissolving the metal, or the Oxide of Lead,
in _excess_ of Nitric Acid, diluted with 2 parts of water. It crystallizes
on evaporation in white anhydrous tetrahedra and octahedra, which are
hard, and decrepitate on being heated; they are soluble in 8 parts of
water at 60°.
Nitrate of Lead forms with Sulphuric Acid, or soluble Sulphates, a white
precipitate, which is the insoluble Sulphate of Lead. The _Iodide_ of Lead
is also very sparingly soluble in water.
NITRATE OF SILVER, _See_ Silver, Nitrate or.
NITRO-GLUCOSE.
When 3 fluid ounces of cold Nitro-Sulphuric Acid, consisting of 2 ounces
of Oil of Vitriol and 1 ounce of highly concentrated Nitric Acid, are
mixed with 1 ounce of finely powdered Cane Sugar, there is formed at first
a thin, transparent, pasty mass. If it is stirred with a glass rod for a
few minutes without interruption, the paste coagulates as it were, and
separates from the liquid as a thick tenacious mass, aggregating into
lumps, which can easily be removed from the acid mixture.
This substance has a very acid and intensely bitter taste. Kneaded in
warm water until the latter no longer reddens litmus-paper, it acquires a
silver colour and a beautiful silky lustre. It may be used in Photography
to confer intensity upon newly mixed Collodion; but is inferior to
Glycyrrhizine employed for the same purpose.
NITRO-HYDROCHLORIC ACID.
Symbol, NO{4} + Cl.
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