A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
Caseine combines with Oxide of Silver in the same manner as Albumen,
forming a white coagulum, which becomes _brick-red_ on exposure to light.
Sugar of Milk, the third principal constituent, differs from both
cane and grape sugar; it may be obtained by evaporating _whey_ until
crystallization begins to take place. It is hard and gritty, and only
slightly sweet; slowly soluble, without forming a syrup, in about two and
a half parts of boiling, and six of cold water. It does not ferment and
form Alcohol on the addition of yeast, like grape sugar, but by the action
of _decomposing animal matter_ is converted into Lactic Acid.
When skimmed Milk is exposed to the air for some hours, it gradually
becomes _sour_, from Lactic Acid formed in this way; and if then heated to
ebullition, the Caseine coagulates very perfectly.
NITRIC ACID.
Symbol, NO{5}. Atomic weight, 54.
Nitric Acid, or _Aqua-fortis_, is prepared by adding Sulphuric Acid to
Nitrate of Potash, and distilling the mixture in a retort. Sulphate
of Potash and free Nitric Acid are formed, the latter of which, being
volatile, distils over in combination with one atom of water previously
united with the Sulphuric Acid.
_Properties._--Anhydrous Nitric Acid is a solid substance, white and
crystalline, but it cannot be prepared except by an expensive and
complicated process.
The concentrated _liquid_ Nitric Acid contains 1 atom of water, and has
a sp. gr. of about 1·5; if perfectly pure, it is colourless, but usually
it has a slight yellow tint, from partial decomposition into Peroxide of
Nitrogen: it fumes strongly in the air.
The strength of commercial Nitric Acid is subject to much variation. An
acid of sp. gr. 1·42, containing about 4 atoms of water, is commonly
met with. If the specific gravity is much lower than this (less than
1·36), it will scarcely be adapted for the preparation of Pyroxyline.
The yellow _Nitrous Acid_, so called, is a strong Nitric Acid partially
saturated with the brown vapours of Peroxide of Nitrogen; it has a high
specific gravity, but this is somewhat deceptive, being caused in part by
the presence of the Peroxide. On mixing with Sulphuric Acid, the colour
disappears, a compound being formed which has been termed a _Sulphate of
Nitrous Acid_.
In the Appendix a Table is given which exhibits the quantity of real
anhydrous Nitric Acid contained in samples of different densities.
_Chemical Properties._--Nitric Acid is a powerful oxidizing agent (see
page 13); it dissolves all the common metals, with the exception of Gold
and Platinum. Animal substances, such as the cuticle, nails, etc., are
tinged of a permanent yellow colour, and deeply corroded by a prolonged
application. Nitric Acid forms a numerous class of salts, _all of which
are soluble in water_. Hence its presence cannot be determined by any
precipitating reagent, in the same manner as that of Hydrochloric and
Sulphuric Acid.
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