A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The chain of chemical affinities is more complete in this diagram than
in the last, where an atom of water only was present, the affinity of
Iodine for Silver being greater than that of Iodine for Hydrogen. Hence
it is possible that an excess of Nitrate of Silver may, by furnishing an
elementary basis for which Iodine has an attraction, assist in drawing off
that element, so to speak, from the original particle of Iodide of Silver
touched by light.[9]
[9] The reader must not suppose from the remarks which have been made in
this Section that images obtained by development consist invariably of
pure metallic Silver. It can be shown that such is not the case,--that the
process of reduction is in many cases suspended when a part only of the
Oxygen has been removed; and hence results a _subsalt_ similar to that
produced by the direct action of light upon organic compounds of Silver,
and differing in properties from metallic Silver. For further particulars
see the Author's Photographic researches in the eighth Chapter.
SECTION III.
_The formation and development of the Latent Image._
It was shown in the second Chapter that the continued action of white
light upon certain of the Salts of Silver resulted in the separation
of elements like Chlorine and Oxygen and the partial reduction of the
compound. We have also seen that bodies possessing affinity for Oxygen,
such as Sulphate of Iron and Pyrogallic Acid, tend to produce a similar
effect; acting in some cases with great energy and precipitating metallic
Silver in a pure state.
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