A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
In summing up the different conditions of the Nitrate Bath which affect
the development of the image, as many as _four_ might be mentioned, each
of which gives a more rapid reduction than the one which precedes it.
These are--the acid Nitrate Bath, the neutral Bath, the Bath of strongly
fused Nitrate of Silver, and the Bath containing _Ammoniacal_ Nitrate of
Silver, which is quite unmanageable, and produces an instantaneous and
universal blackening of the film on the application of the developer.
Greater intensity of image is commonly obtained in a Nitrate Bath which
has been a long time in use, than in a newly mixed solution: this may be
due to minute quantities of organic matter dissolved out of the Collodion
film, which, having an affinity for Oxygen, partially reduce the Nitrate
of Silver; and also to the accumulation of Alcohol and Ether in an old
Bath producing a short and friable structure of the film.
i. _Effect of Temperature on Development._--Reduction of the oxides of
noble metals proceeds more rapidly in proportion as the temperature
rises. In cold weather it will be found that the development of the image
is slower than usual, and that greater strength of the reducing agent and
more free Nitrate of Silver is required to produce the effect.
On the other hand, if the heat of the atmosphere be excessive, the
tendency to rapid reduction will be greatly increased, the solutions
decomposing each other almost immediately on mixing. In this case the
remedy will be to use Acetic Acid _freely_ both in the Bath and in the
developer, at the same time lessening the quantity of Pyrogallic Acid, and
omitting the Nitrate of Silver which is sometimes added towards the end of
the development.
Also in the case of films which are to be kept for a long time in a
sensitive condition by means of honey, etc., the modifying influence of
temperature must be observed, and the quantity of free Nitrate of Silver
left upon the film be reduced to a minimum if the thermometer stands
higher than usual.
SECTION IV.
_On certain Irregularities in the Developing Process._
The characteristics of the proper development of a latent image are--that
the action of the reducing agent should cause a blackening of the Iodide
in the parts touched by light, but produce no effect upon those which have
remained in shadow.
In operating both on Collodion and paper however there is a liability to
failure in this respect; the film beginning, after the application of the
developer, to change in colour to a greater or less extent over the whole
surface.
There are two main causes which produce this state of things:--the first
being due to an irregularity in the action of the light; the second to a
faulty condition of the chemicals employed.
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