A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
It must be premised however, that the same degree of excellence is not to
be expected in a Negative Photograph which has been improperly developed
in the first instance and more especially if the exposure to light was
too short. Any "instantaneous Positive" may be rendered sufficiently
intense for a Negative, but in that case the shadows are almost invariably
imperfect.
1. _Treatment of the image with Sulphuretted Hydrogen or Hydrosulphate of
Ammonia._--The object is to convert the metallic Silver into _Sulphuret
of Silver_, and if this could be done it would be of service. The mere
application of an Alkaline Sulphuret has however but little effect upon
the image, excepting to darken its surface and destroy the Positive
appearance by reflected light; the structure of the metallic deposit being
too dense to admit of the Sulphur reaching its interior.
Professor Donny ('Photographic Journal,' vol. i.) proposes to obviate this
by first converting the image into the white Salt of Mercury and Silver by
the application of Bichloride of Mercury, and afterwards treating it with
solution of Sulphuretted Hydrogen or Hydrosulphate of Ammonia. Negatives
produced in this way are of a brown-yellow colour by transmitted light,
and opaque to chemical rays to an extent which would not, _à priori_, have
been anticipated.
2. _MM. Barreswil and Davanne's process._--The image is converted into
Iodide of Silver by treating it with a saturated solution of Iodine in
water. It is then washed--to remove the excess of Iodine,--exposed to
the light, and a portion of the ordinary developing solution, mixed with
Nitrate of Silver, poured over it. The changes which ensue are precisely
the same as those already described; the whole object of the process being
to bring the metallic surface back again into the condition of Iodide of
Silver modified by light, that the developing action may be commenced
afresh, and more Silver deposited from the Nitrate in the usual way.
3. _The process with Bichloride of Mercury and Ammonia._--The image is
first converted into the usual white double Salt of Mercury and Silver
by the application of a solution of the Corrosive Sublimate. It is then
treated with Ammonia, the effect of which is to _blacken_ it intensely.
Probably the alkali acts by converting Chloride of Mercury into the black
Oxide of Mercury. In place of Ammonia, a dilute solution of Hyposulphite
of Soda or Cyanide of Potassium may be used, with very similar results.
CHAPTER VIII.
ON THE THEORY OF POSITIVE PRINTING.
The subject of Collodion Negatives having been explained in the previous
Chapter, we proceed to show how they may be made to yield an indefinite
number of copies with the lights and shadows correct as in nature.
Such copies are termed "Positives," or sometimes "Positive prints," to
distinguish them from direct Positives upon Collodion.
Public-domain text, read in full here on John Shaqi.
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