A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
The free Nitrate of Silver increases the instability of the Gold salts;
but if present in too great an excess, it is apt to cause a decomposition
of Hyposulphite of Silver, and consequent yellowness in the white parts
of the proof. It is therefore particularly recommended to wash the print
in water before immersing it in the fixing and toning Bath.
c. _Temperature of the solution._--In cold weather, the thermometer
standing at 32° to 40°, the Bath works more slowly than usual; whereas
in the height of summer, and especially in hot climates, it occasionally
becomes quite unmanageable. The best temperature for operating
successfully appears to be about 60° to 65° Fahrenheit; if higher than
this the solutions must be employed more dilute.
d. _Addition of Iodide of Silver._--Some operators associate Iodide with
Chloride in the preparation of sensitive paper for printing. Another
source of the same salts is the admixture of a portion of the fixing Bath
used for Negatives with the Positive toning solution. The presence of
Iodides in the fixing and toning Bath is injurious: when in large excess,
they dissolve the image, or produce yellow patches of Iodide of Silver on
the lights; in smaller quantity, the deposition of the Gold is hindered,
and the action proceeds more slowly. Bromides and Chlorides have not the
same effect.
e. _Mode of preparing the paper._--The rapidity of toning varies with
causes independent of the Bath: thus, plain paper prints are toned more
quickly than prints upon albuminized paper, and the use of English paper
sized with Gelatine retards the action. Foreign papers rendered sensitive
with Ammonio-Nitrate tone the most quickly.
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