A still more conclusive proof is furnished by the behaviour of substances
which exist in the form of gases. If a jar is filled with one gas, a
second and third gas can be poured into it as readily as into a vacuum,
the result being that the pressure on the sides of the jar is exactly
equal to the sum of the separate pressures of each separate gas. This
evidently means that the first gas does not occupy the whole space, but
that its particles are like a battalion of soldiers in loose skirmishing
order, with such intervals between each unit that a second and third
battalion can be marched in and placed on the same ground, without
disturbing the formation, and with the result only of increasing the
intensity of the fire.
Now gas is matter as much as solids or liquids, and in the familiar
instance of water we see that it is merely a question of more or less
heat whether the same matter exists as ice, water, or steam. The number
and nature of the molecules is not changed, only in the one case they are
close to one another and solidly linked together; in the other, further
removed and free to move about one another, though still held together
as a mass by their mutual attractions; and in the third, still further
apart, so that their mutual attraction is lost and they dart about, each
with its own proper motion, bombarding the surface which contains them,
and by the resultant of their impacts producing pressure.
In this latter and simpler form of gas the following laws are found to
prevail universally for all substances. Under like conditions volumes
vary directly as the temperature and inversely as the pressure. That
is to say, the pressure which contains them remaining the same, equal
volumes of air, steam, or any other substance in the state of gas, expand
into twice the volume if the temperature is doubled, three times if it
is tripled, and so on; contracting in the same way if the temperature
is lowered. If on the other hand the temperature remains constant, the
volume is reduced to one half or one third, if the pressure is doubled
or tripled. From these laws the further grand generalisation has been
arrived at, that all substances existing in the form of gas contain the
same number of molecules in the same volume.
This, which is known as the Law of Avogadro, from the Italian chemist by
whom it was first discovered, is the fundamental law of modern chemistry,
and the key to all certain and scientific knowledge of the constitution
of matter and of the domain of the infinitely small, just as much as the
law of gravity is to action of matter in the mass, and the resulting
conditions and motions of mechanics and astronomy.
Public-domain text, read in full here on John Shaqi.
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