If nitrogen had more affinity for oxygen it would
combine chemically with it, and we should live in an atmosphere of
nitrous oxide, or laughing gas.
The molecule, therefore, of nitro-glycerine resembles a house of cards,
so nicely balanced that it will just stand, but will fall to pieces at
the slightest touch. When this is supplied by a slight percussion the
molecule falls to pieces and is resolved into its constituent atoms,
which rush together in accordance with their natural affinities, forming
an immense volume of gas, partly of water in the form of steam where
oxygen has combined with hydrogen, and partly of carbonic dioxide where
it has combined with carbon, leaving the nitrogen atoms to pair off, and
revert to their original form of two-atom molecules of nitrogen gas.
It is as if ill-assorted couples, who had been united by matrimonial
bonds tied by the manœuvres of Belgravian mothers, found themselves
suddenly freed by a decree of divorce _a vinculo matrimonii_, and rushed
impetuously into each other’s arms, according to the laws of their
respective affinities. So striking is the similitude that one of Goethe’s
best-known novels, the ‘Wahlverwandschaften,’ takes its title from the
human play of these chemical reactions. The enormous energy developed
when these atomic forces are let loose and a vast volume of gas almost
instantaneously created, is attested by the destructive force by which
the hardest rocks are shattered to pieces and the strongest buildings
overthrown.
These loves and hatreds, or, as they are termed, chemical affinities and
repulsions of the atoms, are the principal means by which the material
structure of the universe is built up from the original elements.
The earth, or solid crust of the planet we inhabit, consists mainly
of oxidised bases, and is due to the affinity of oxygen for silicon,
calcium, aluminium, iron, and other primary elements of what are called
metals. This affinity enables them to make stable compounds, which, under
the existing conditions of temperature and otherwise, hold together and
are not readily decomposed. Water in like manner, in all its forms of
waves, seas, lakes, rivers, clouds, and invisible vapour, is due to the
affinity between oxygen and hydrogen forming a stable compound. Salt
again is owing to the affinity of chlorine for sodium, and so for nearly
all the various products with which we are familiar, oxygen and nitrogen
in the air we breathe being almost the only elements which exist in their
primary and uncombined state in any considerable quantities, and form
an essential part of the conditions which render our planet a habitable
abode for man and other forms of life.
We shall see presently something more of the nature of these affinities,
and the laws by which they act; but before entering on this branch
of the subject we must consider the remaining form in which the one
indestructible energy of the universe manifests itself, viz. that of
electricity.
Public-domain text, read in full here on John Shaqi.
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