As I began with the illustration of the magnet introducing order and
harmony into the confused mass of iron filings, let me take this other
illustration from the same source. If we place an iron bar in contact
with the pole of a magnet, the bar becomes itself a magnet with opposite
poles to the original one, so that as opposite poles attract, the iron
bar adheres to it. Bring a lump of nickel in contact with the further end
or free pole of the iron bar, and the nickel also will be magnetised and
adhere. Let the lump of nickel be as large as the pole of the iron bar
is able to support, and now bring a lump of soft iron near this pole. It
will drop the nickel and take the iron. This is exactly similar to those
cases of chemical affinity in which a molecule drops one of its factors
and takes on another to which its attraction is stronger. If iron rusts
in water it is because the oxygen atom drops hydrogen to take iron just
as the magnet dropped nickel.
The polarity of chemical elements is attested by the fact that when
compounds are decomposed by the electric current, the different
elementary substances appear at different poles of the battery. Thus,
oxygen, chlorine, and non-metallic substances appear at the positive
pole; while hydrogen, potassium, and metals generally, appear at the
negative one. The inference is irresistible that the atoms had in each
case an opposite polarity to that of the poles to which they were
attracted. This is confirmed by the fact that the radicals, i.e. the
elementary atoms or groups of atoms which have opposite polarities,
combine readily; while those which have the same polarity, as two
metals, have but slight affinity for each other. Like therefore attracts
unlike, as in all cases of polarity, and the greater the degree of
unlikeness the stronger is the attraction. Thus, the radicals of all
alkalies are electro-positive, and appear at the negative pole of a
battery; while those of acids are all electro-negative, and the higher
each stands in its respective scale of polarity the more strongly does it
show the peculiar qualities of acid or alkali and the more eagerly does
it combine with its opposite.
Acids and alkalies are, in fact, all members of the same class of
compounds called _hydrates_, because a single atom of hydrogen is a
common feature in their composition. This atom is coupled with a single
atom of oxygen, which may be conceived of as the central magnet holding
the hydrogen atom at one pole, while at the other it holds either a
single atom of some metallic element, such as potassium or sodium, or a
group consisting of such an element together with atoms of oxygen, so
constituted as to present a single pole to the attraction of the central
oxygen atom. Thus, if K stands for kali or potassium, N for nitrogen, O
for oxygen, and H for hydrogen, we may have the compounds
H—O—K
and
{ O}
{ / }
H—O—{N }.
{ \ }
{ O}
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