A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
On considering all the circumstances, I am inclined to believe, that
the properties which distinguish steel from iron are rather owing to a
peculiar crystallization or arrangement of the ultimate particles of
iron, than to their combination with carbone or any other substance.
In all cases where steel is formed, the mass is brought into a liquid
form, or nearly approaching to it, a circumstance which allows the
particles to be subject to the law of crystallization. We see that
great change is made in steel by the mere _tempering_ of it, which
cannot be ascribed to the loss or gain of any substance, but to some
modification of the internal arrangement of its particles. Why then
may not its differences from iron be ascribed to the same cause? It is
allowed that steel, by being repeatedly heated and hammered, becomes
iron: that is, it should seem, the change of figure disturbs the
regular arrangement of the particles. And it may be further observed,
in corroboration of the opinion that cast iron is capable of being made
permanently magnetic, from its having been in fusion more probably than
from its near approximation to steel in its component parts. The most
powerful artificial magnets, after being forged of steel, are said to
undergo the operation of steelifying again, before they are hardened
finally to receive the magnetic virtue.
SECTION 17.
METALLIC ALLOYS.
When two or more metals of different specific gravities are melted
together and intimately mixed, they frequently enter into chemical
union and form a new compound, called an alloy of the metals. These
alloys often possess important properties which their constituents
singly do not, and hence become valuable acquisitions to the arts.
The metals thus combined may be fused together in any proportion; but
if one of them greatly exceed the other in specific gravity, their
intimate union is sometimes rendered difficult and even impracticable,
partly from the weak affinity and partly from the gravitating principle
causing the metal of least specific gravity to arise to the surface.
Notwithstanding this union of metals in seemingly indefinite
proportions, there are only a few proportions in which the alloys
possess peculiar excellences so as to entitle them to the attention of
artists. These proportions have in many instances been discovered by
experience; and it only remains for theory to point out the reason for
such proportions, and to suggest other proportions which may bid fair
to possess desirable qualities, and thereby diminish the unsuccessful
attempts for improvement in these combinations.
That the metals thus alloyed constitute true chemical compounds and not
merely mechanical mixtures, may be inferred from the change made in
their primary qualities; such as
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