A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
1. _Tenacity_, _hardness_, &c. Some alloys are
much superior to their ingredients in tenacity and hardness,
whilst others affect a kind of medium between them. This
last is often the case too in regard to ductility and
malleability.
2. _Fusibility._ Several alloys fuse at temperatures
intermediate between the fusing temperatures of their
ingredients, but mostly lower than the mean; there are
others which fuse below the temperature of the lowest, and
few if any require a temperature above the mean for their
fusion.
3. _Colour._ In many cases the colour of alloys is such
as would be produced by the mixture of the colours of the
metals; but in others, remarkably different; for instance,
the alloys of copper and zinc,--forming the various kinds of
brass.
4. _Specific gravity._ This is not always what might be
inferred from a mixture of the two ingredients. Sometimes
it is greater and other times less; but this is not a
decisive mark of chemical union, as the same metal varies
in specific gravity, by hammering, rolling, tempering, &c.
very considerably. Besides, it is more than probable that
the differences said to have been observed, have in some
instances arisen from inaccurate experiments; as it is a
delicate operation to find the specific gravity of small
pieces of metal with sufficient precision for comparisons of
this kind.
Many of the simple metals, when fused and exposed to the air for some
time, without a covering of charcoal, or some similar principle,
acquire less or more of oxygen, and retain it even in a fluid state,
as is proved from Mr. Lucas’s interesting communication in the 3d Vol.
of the Manchester Society’s Memoirs (new series). Hence by frequent
fusions of the same metal its quality becomes impaired in regard to
tenuity and other properties.
This is more eminently the case with regard to alloys. Thus, zinc
at the temperature in which brass melts is combustible; and hence a
portion of it escapes by combustion. Hence the proportions of brass are
changed less or more at each fusion, unless fresh zinc be added. The
same observation applies to alloys of copper and tin with regard to
the tin. The mixtures of lead, tin, bismuth and other soft and easily
fused metals, are still more remarkable in this respect. They should be
fused under a cover of oil or tallow in order to keep them of the same
proportions; otherwise, some of them, particularly the tin, is liable
to great oxidation, and no two successive fusions will present the
same alloy. Hence in some degree the use of fluxes in metallurgy which
serve to cover the surface of the metals and prevent oxidation from the
atmosphere.
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