A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
9. _Silver and arsenic._ These two metals unite according to Bergman,
the fused silver taking up ¹/₁₄ of its weight of arsenic; the alloy
corresponds nearly to 3 atoms silver and 1 arsenic. It is brittle and
of a yellowish colour.
_Alloys of Mercury and other Metals: Amalgams._
The alloys of Mercury with the various metals have been commonly
denominated amalgams.
1. _Mercury and gold._ Gold amalgamates pretty easily with mercury and
forms an alloy much used in gilding metals. For this purpose six parts
of mercury may be heated nearly to the ebullition of the liquid, and
one part of pure gold in thin plates may be gradually added. In a few
minutes the whole becomes one fluid mass of a yellowish white colour.
It is constituted of 1 atom of gold and 2 of mercury. By squeezing it
through leather one half of the mercury is separated nearly pure, and
the other remains combined with the gold, and forms a soft white mass,
consisting of 1 part gold and 2½ mercury nearly, which is the alloy of
1 atom to 1, and may be subsequently used for gilding. A ready way of
making this amalgam I find is to put 3 parts of gold, precipitated by
green sulphate of iron, to 8½ or 9 parts of mercury; by a few minutes
trituration the whole becomes a fine crystalline amalgam.--When this
amalgam of gold is exposed to a heat just below red, the mercury
sublimes and leaves the gold; hence its use in gilding.
2. _Mercury and platina._ These two metals may be combined, but not
very easily, as little affinity seems to exist betwixt them. This is
manifest from the circumstance that platina wire may be long immersed
in mercury without any sensible effect. An union may be produced by
immersing thin platina foil into boiling mercury for some time; also by
triturating the ammonio-muriate of platina with mercury and exposing it
to a due heat. The proportions have not been determined.
3. _Mercury and silver._ Silver and mercury have a considerable
affinity and are easily combined by putting lamina of silver into
heated mercury and agitating the mixture. When 1 part silver and 2
mercury are mixed as above, a fluid mass is obtained which being heated
to the temperature of boiling mercury, a little mercury evaporates
and the remainder crystallizes into a soft white mass, which in time
grows hard and brittle. A higher heat than boiling mercury expels the
mercury. Hence this amalgam may be used for giving a thin coating of
silver to the surface of metals, like that of gold. The compound is
evidently one atom of silver (90) with one of mercury (167).
4. _Mercury and copper._ I have made several unsuccessful attempts to
combine mercury and copper.
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