A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The mode of analysis I adopted with compounds of copper and tin, is
simple and easy. The alloy is treated with nitric acid, which dissolves
the copper, and on being diluted with water throws down the tin in
the state of deutoxide. This last is collected on a filtre, dried,
and heated to a low red; then ²⁶/₃₃ of this is allowed for the tin
(the other 7 parts being oxygen); and the rest of the alloy may be
considered as copper. But if thought proper the copper may be thrown
down by immersing a plate of lead in the solution, which succeeds
better than a plate of iron in nitric solutions of copper.
4. _Copper and lead._ Copper unites with boiling lead and forms a grey
brittle alloy of granular texture. This alloy being heated above the
melting point of lead, causes the last metal to run off, leaving the
copper nearly pure. The alloy is scarcely of any use.
5. _Copper and zinc._ Copper and zinc combined form _brass_, one of
the most useful of all alloys. Though this is a general name for such
combinations, yet several of the proportions form compounds to which
peculiar names are given, some of which will be noticed below.
It may be proper to remark that copper is estimated by Mr. Kirwan
at 7½° in hardness, whilst zinc is 6½. The former metal is highly
tenacious and malleable; the latter is brittle and malleable only in
a small degree. According to Lewis a very small proportion of zinc
dilutes the colour of copper and renders it pale; when the copper
has imbibed ¹/₁₂ of its weight, the colour inclines to yellow. The
yellowness increases with the zinc till the weight of that metal in the
alloy equals the copper. Beyond this point if the zinc be increased the
alloy becomes paler and paler and at last white, like zinc.
The tenacity of brass is greater than that of either copper or zinc
according to Muschenbroek. His experiments give brass nearly twice as
strong as copper, and 18 times as strong as zinc. It seems to me most
probable that the tenacity of brass increases with the increase of zinc
in the alloy to a certain proportion, when it becomes a maximum, and
thence diminishes with the further increase of zinc, but experiments
are yet wanting, I presume, to ascertain what proportion of the two
metals must be taken to form the alloy of greatest tenacity. The
same observation may be made as to the maximum hardness; it is not
improbable that the two maxima may be found in different kinds of
brass.
The point of temperature at which copper fuses is stated to be 27° of
Wedgwood’s thermometer, whilst that of zinc is much lower, namely, 680°
of Fahrenheit. Common brass is stated to melt at 21° of Wedgwood. It is
very probable that all kinds of brass melt at temperatures intermediate
between those of copper and zinc; and that the more of zinc the
lower will be the fusing temperature; but there have not been direct
experiments to ascertain the degrees, as far as I know.
Public-domain text, read in full here on John Shaqi.
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