A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
In enumerating the different proportions of such alloys as have come
under my notice I shall begin with that containing the maximum of
copper, and proceed in gradation to that with the maximum of zinc.
(_a_). _Brass for the manufacture of plated goods._ This alloy is
composed, judging from one specimen I analysed, of 12 atoms of copper
and 1 of zinc; or of nearly 28 parts of copper by weight and 1 of zinc.
The atom of copper is here estimated at 56 and that of zinc at 29, or
very nearly ½ that of copper. This alloy had much the same qualities
apparently as copper itself, only a little more yellow.
(_b_). _Dutch gold, gilding metal._ This is the alloy which may be
beaten out into thin leaves, after the manner of gold leaf. I have not
been able to find any proportions for this compound in books. It seems
to have been kept as a secret by the manufacturers. By analysis however
I find it composed of 6 atoms of copper and 1 of zinc, or nearly 12
parts copper and 1 zinc by weight. This alloy is probably the most
malleable of all the kinds of brass. A leaf containing 12 square inches
weighs about ⁷/₁₀ of a grain. The colour, as is well known, makes a
good approach to that of gold. It is the composition used for making
articles to be gilt, as buttons, &c.
(_c_). _Dipping metal for stamped brass goods._ This is a well known
article of Birmingham manufacture. It is an alloy both tenacious and
malleable, as is manifest from the perfection of the articles. It
possesses a beautiful gold colour. A specimen was composed, by my
analysis, of 4 atoms of copper to 1 of zinc; or of 8 lbs. of copper and
1 of zinc; or of 4 lbs. copper and 3 of common brass; but it is varied
according to the colour wanted.
(_d_). _Soft, fine coloured brass._ According to M. Sage, a very
fine kind of brass may be made by mixing oxide of copper, calamine,
black-flux and charcoal powder together and fusing the mixture in a
crucible till the blue flame disappears. The brass is found to weigh ⅙
more than the copper resulting from the weight of oxide. He says when
the copper retains ⅕ of zinc the colour is not so fine; and the excess
of zinc will be burned off by heat, but the zinc cannot be reduced by
burning below ⅙; so that this appears to be a natural limit. Hence
this compound, being formed of 6 parts copper and 1 of zinc, must be
constituted of 3 atoms of copper and 1 of zinc.
(_e_). _Soft brass preferred for watch movements._ There is a kind
of brass greatly preferred by watch-makers on account of its working
well with steel. I have not met with a specimen; but Dr. Thomson has
analysed one and found it to consist of 2 atoms of copper and 1 of
zinc;[22] or 4 parts copper and 1 of zinc by weight nearly.
[Footnote 22: An. of Philos. Vol. 12.]
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