A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Besides the binary combinations of copper and zinc and copper and tin,
there are _ternary_ combinations of these metals, namely, alloys of
copper, zinc and tin. For instance, the metal of which common white
buttons are made. I had occasion to analyse a specimen of this metal
and found it to be constituted of 4 parts copper, 1 of zinc and 1 of
tin; or 4 atoms of copper, 2 of zinc and 1 of tin.
It will be proper to subjoin the methods of analysis which I adopted
in regard to brass. Twenty grains, more or less, of the particular
articles were dissolved in nitric acid, and the metals were
precipitated in the state of sulphurets by hydrosulphuret of lime.
The copper is thrown down in the state of a black powder, and the
zinc in that of a white powder turning to grey. Great care was taken
to add the precipitating liquor gradually in order that the copper
might be obtained distinctly from the zinc. The whole of the copper
is thus thrown down before any of the zinc precipitate appears. The
precipitates were collected and dried in a temperature not exceeding
150°, and then weighed. In both cases one third of the weight was
allowed for sulphur, and the remaining two thirds were estimated to
be metal; which is agreeable to the known constitutions of these
sulphurets. Another method I sometimes practised, which also answers
very well; namely, to throw down the whole or greatest part of the
copper by a plate of lead, then to throw down the lead by sulphuric
acid; after this the liquor was tested by hydrosulphuret of lime to
precipitate the copper remaining, if any; and lastly to throw down the
zinc by hydrosulphuret of lime.
6. _Copper and bismuth._ The alloy is brittle and of a pale colour. It
is not much known.
7. _Copper with antimony._ Copper and antimony unite by fusion and form
a violet coloured, brittle alloy.
8. _Copper and arsenic._ These metals unite by fusion in a close
crucible, the surface of the mixture being covered with common salt
to prevent the oxidizement of the arsenic. The alloy is white and
brittle, and is known by the names of _white copper_, and _white
tombac_.
9. _Copper and manganese._ These may be united by fusion, and form a
red coloured, malleable alloy, according to Bergman.
10. _Copper and molybdenum._ These metals may be alloyed in various
proportions, but the compounds exhibit nothing peculiarly remarkable.
_Alloys of Iron with other Metals._
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