A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
(_f_). _Common hard brass._ This constitutes the great bulk of brass,
as manufactured in the large way. It is made by exposing granulated
copper, calamine, that is, a native oxide of zinc, and powdered
charcoal in mixture to a red heat for some hours, and then increasing
the heat so as to melt the compound of copper and zinc, the charcoal
having carried away the oxygen of the calamine. The metal is then cast
into ingots or plates as may be required. This is called brass of
cementation as distinguished from the other species, which are usually
made from this by fusion with copper or zinc as the case requires.
It is found that 40lbs. of copper with 60lbs. of calamine yield 60 lbs.
of brass; hence a great part of the zinc burns away during the process.
The brass thus resulting, consisting of 2 parts of copper and 1 of
zinc, is of course constituted of 1 atom of each metal united together.
Common brass is malleable, when cold, like the preceding species;
but probably does not possess that property in so high a degree. It
seems better adapted for turning in the lathe than any other kind of
brass. The specific gravity of this brass before it is hammered or
rolled is generally about 8.1 or 8.2 by my experience. When rolled it
receives a great increase of density, amounting to .5 according to M.
Dussaussoy[23], so that what is 8.2 when cast will be 8.7 when rolled;
or it is condensed nearly ¹/₁₆ of its volume by the operation of
rolling. The same author finds that brass is hardened very considerably
by rolling, but rendered less tenacious; however by being heated and
consequently softened after rolling, it becomes stronger than ever,
and nearly of an intermediate specific gravity between cast and rolled
brass.
[Footnote 23: An. de Chim. & Physique. 5--233.]
(_g_). _Prince’s metal, pinchbeck_, &c. This compound, as far as I can
learn, is usually formed by combining equal weights of copper and zinc,
or by fusing together 3 parts of common brass with 1 of zinc. According
to Lewis the yellow colour of brass is a maximum in this proportion.
The alloy is brittle, or at least much less malleable than common
brass. I find the composition of _spelter_ solder, as it is called, or
that used for soldering both brass and copper, to be nearly equal parts
of copper and zinc. Hence it appears that 1 atom of copper unites to 2
of zinc to form this alloy.
The other alloys of copper and zinc in which the zinc gradually
exceeds the copper, become gradually paler in colour and more brittle.
They do not promise to be of much utility in the arts, and have not
therefore been very particularly investigated by metallurgists.
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