A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The middle sized types are made of metal composed of 1 atom of
antimony and 2 of lead, or 40 parts antimony and 180 of lead. This
alloy fuses about 450° or 460° and has the specific gravity of 10
nearly.
The largest types or letters of 2 or 3 inches diameter are made of
metal composed of 1 atom antimony and 3 of lead, or 40 parts to 270.
This alloy also fuses about 450 or 460°, which is a very remarkable
fact. Its specific gravity is usually 10.22. After several trials I
could not determine whether the fusing point of this or the preceding
alloy was lower; and equal parts of the two alloys fused together were
liquified at the same temperature of 450 or 460°.
All the intermediate sizes of types appear to be made of one or other
of the three preceding proportions or of mixtures of them, the smaller
the type the more of antimony being required to give the requisite
hardness. The largest types might, I conceive, be made with a much
greater proportion of lead.
When 40 antimony and 360 lead (1 atom to 4) are fused together, the
melting point is about 470°. The specific gravity was found 10.4, but
probably too low from blisters or air bubbles. The alloy was more
flexible than the preceding, but brittle with a fine grained fracture.
Forty parts antimony with 450 lead (1 atom to 5) fused at 490°, and
gave 11 specific gravity. This alloy bends and breaks with a fine
grained fracture.
Forty parts antimony with 540 lead (1 atom to 6) fused at 510°, and
gave 10.8 specific gravity, which in all probability was owing to air
bubbles. Now the alloy soft and malleable.
4. _Lead and arsenic._ When lead is fused in contact with the white
oxide of arsenic under a film of tallow and stirred frequently, an
union of the two metals takes place and the excess of white oxide is
partially converted into arsenic and partly driven off, seemingly
taking with it a portion of the lead. A considerable portion of
the mass assumes the form of a black spongy compound infusible at
the temperature. It contains a portion of the lead and is probably
a compound of the metals with oxygen. The fusible alloy has the
appearance of lead, but is brittle, breaks without bending and exhibits
a fracture like that of antimony and lead. The specific gravity of the
alloy is 10.6, or more if not saturated with lead. By treating it with
an excess of nitric acid it is dissolved, and the lead may be thrown
down by sulphuric acid, and the arsenic acid or oxide by lime. In this
way I find the alloy is composed of about 9 parts of lead with 2 of
arsenic, or 1 atom of each of the metals. The spongy mass treated with
nitric acid yields a similar solution, accompanied with a precipitation
of oxide of arsenic.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account