A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
5. _Lead and cobalt._ The alloy of these two metals is not easily
obtained, probably from the great difference of the temperature at
which they fuse. Gmelin fused 1 part cobalt with 1, 2, 4, 6 and 8
parts of lead respectively. Alloys were obtained of the specific
gravities 8.12, 12.28 (query 8.28?), --, 9.65 and 9.78 respectively.
From these specific gravities it is plain the lead had been in great
part dissipated by the heat. For the last or greatest specific gravity
corresponds nearly to 2 parts lead and 1 of cobalt. (An. de Chimie,
19--357.)
_Triple Alloys, Solders; Fusible Metal, &c._
Though it may seem premature to treat of triple compounds in the
present chapter, which professedly is limited to compounds of two
elements, yet as the triple alloys are few and so immediately connected
with the preceding, it will scarcely require an apology for introducing
them here.
_Soft solders._ Solders for plumbers and tin-workers, are required
to melt easily, and yet not too low, as they should withstand a heat
greater than boiling water. The fusing point of the soft solders is
usually between 300-400°. Plumbers’ solder I believe is commonly
formed by mixing equal parts of tin and lead. I procured a specimen of
8.9 specific gravity, and its fusing point was 380°. Probably a more
perfect compound would be formed by mixing 104 parts tin with 90 lead
(2 atoms to 1), which would give a specific gravity of 8.8 and the
fusing point 350°.
Tin workers’ solder is made rather more fusible than that of the
plumbers. A specimen I got from the workmen was 8.87 specific gravity
and fused at 345°. A mixture of 3 parts tin and 2 of lead would have
formed an alloy of the same fusibility, but the specific gravity would
have been 8.6 or 8.7 only. Probably a rather less proportion of tin
with a little bismuth entered into the composition.
_Fusible Metal._ Tin, bismuth and lead are metals which melt at
comparatively low temperatures; and it has been shewn that the alloys
of any two of them usually melt at lower temperatures than the mean,
or even than the lower extreme. By analogy it might be inferred that
an alloy of tin and lead fused with one of tin and bismuth, would melt
below either of the two ingredients. It has been shewn that proportions
of bismuth and lead of easiest fusion are 2 atoms bismuth with one of
lead; this alloy melts at 250°. An alloy of 2 atoms of bismuth and 1 of
tin melts at 260°; and so does that of 1 atom bismuth and 1 tin. These
alloys being much more easily fused than any other proportions of these
metals, it is from their combinations we are to expect a still further
reduction of the fusing point. In fact, a combination of either of
the tin and bismuth alloys, with the lead and bismuth alloy, produces
almost exactly the same reduction of the fusing temperature.
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