A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
In reference to the experiments of Dulong and Petit, on the relative
expansions of air and mercury by heat, I have no doubt their results
are good approximations to the truth. My former experiments were
chiefly made in temperatures between 32° and 212°, and I found, as
General Roi had done, the expansion of air to be somewhat greater in
the lower half than in the upper half of that interval, compared with
mercury. On a repetition of the experiments, I think the difference is
less than I concluded it to be, and I find that the like coincidence of
the air scale and mercurial, continues down to near freezing mercury;
at least the difference will not be so great as my new table of
temperature makes it at page 14. I have made some experiments on the
expansions of air above 212°, which lead me to adopt the results of
Dulong. On a comparison of the air and mercurial thermometer upon the
laws which I pointed out, namely, the former expanding in geometrical
progression to equal intervals of temperature, and the latter expanding
as the square of the temperature reckoned from its freezing point, it
appears that in the long range of 600° from freezing water to boiling
mercury, the greatest deviation of the two thermometers does not
exceed 22°. However, the great deviation of the scales between the
temperatures of freezing water and freezing mercury, is sufficient to
shew, as Dulong and Petit have observed, that their coincidence is
only partial. Like the scales of air and mercury, which are so nearly
coincident from -40° to 212° that scarcely any difference is sensible,
though no one doubts of its existence; yet afterwards the differences
become obvious enough, and the greater the farther we advance.
_Expansion of Mercury._ See page 34, vol. I. I have overrated the
expansion of glass bulbs (as will be seen presently,) and hence that of
mercury; my expansion of mercury corrected on account of the glass,
will be ¹/₅₃ nearly, which leaves it still greater than Dulong’s.
The 2nd table of Dulong is valuable, on account of its affording
us information of the rate of expansion in the higher degrees of
temperature, from a given or standard air thermometer.
_Iron, Copper, and Platina._
Public-domain text, read in full here on John Shaqi.
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