A new system of chemical philosophy, Volume 2, Part 1Dalton, John
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A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
From the foregoing detail of experiments on elastic fluids, it appears
evident that such fluids exhibit matter under a form in which it has
the greatest possible capacity for heat, when capacity is understood
to denote the total quantity of heat connected with the fluid; but if
the capacity or specific heat is meant to denote the quantity of heat
necessary to raise the body a given number of degrees of temperature,
then the elastic fluid form of matter is that which has the least
capacity for heat of any known form of the same matter. When therefore
we use the terms _specific heat_ as applied to elastic fluids we should
henceforward carefully distinguish in what sense they are used; but the
terms may still be indifferently used in the one or the other sense
as applied to liquids and solids, till some more decisive experiments
shew that a distinction is required. Probably the anomalies that have
occurred in investigations of the zero of cold, or point of total
privation of heat, are in part due to the want of accordance between
the ratio of the total quantities of heat in bodies, and the ratio of
the quantities producing equal increments of temperature.
The greatest possible quantity of heat which a given weight of elastic
fluid can contain is when the dilatation of the fluid is extreme.
For, condensation, whether arising from mechanical pressure or from
increased attraction of the atoms of matter for each other, tends to
dissipate the heat, by increasing its elasticity. Hence increase of
temperature, at the same time that on one account it increases the
absolute quantity of heat in an elastic fluid, diminishes the quantity
on another account by an increase of pressure, if the fluid be not
suffered to dilate. This is well known from the fact that condensation
produces increase of temperature in elastic fluids.
When it is considered that all elastic fluids expand the same quantity
by the same increase of temperature, it might be imagined that all of
them would have the same capacity, or require the same quantity of
heat to produce that expansion. The results of De la Roche and Berard
do not seem to admit of this supposition, though the differences of
the capacities of elastic fluids of equal volumes are not very great.
There is a remarkable difference too between their results and those
of Clement and Desormes, in regard to hydrogen gas: namely, .9033 and
.6640; also in carbonic acid gas, 1.2583 and 1.5. The subject deserves
further investigation.
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