A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
_Capacities of bodies for heat._ In the 5th table of Dulong, we have
the specific heats of glass and of six metals, determined between
freezing and boiling water: that of iron is given before. So far
the question does not involve that of the measure of temperature.
Their results afford no striking differences from those previously
determined; however, it is desirable to find a greater accordance
amongst philosophers in this respect. The experiments which give
the specific heats between 0° and 300° centigrade, are original and
interesting. The results go to shew that the capacities of bodies
increase in a small degree with the temperature. But supposing that
these results may be relied upon as accurate (which can scarcely be
affirmed of any former ones) still the character of them may be changed
by adopting a different measure of temperature.
The Essay of M. M. Dulong and Petit, in the 10th vol. of the An.
de chimie (see An. of Philosophy, vol. 14th, 1819) manifests great
ingenuity. It does not appear, however, so fortunate either in theory
or experiment as the former one. It would be difficult to convince any
one, either by reasoning or by experience that a number of particles
of mercury at the temperature of -40°, whether in the solid,, liquid,
or elastic state, have all the same capacity for heat. Indeed the
experiments of De la Roche and Berard, if they are to be credited,
demonstrate the inferior capacity of condensed air to rarefied air;
and if the same body changes its capacity in the elastic form, it may
well be concluded that all the three forms have not the same capacity.
M. M. Dulong and Petit have themselves shewn, in their former essay,
(see page 276) that solid bodies vary in their capacities for heat,
and that scarcely any two bodies, vary alike; hence it is impossible
that the product of the weight of the atom and specific heat of the
body should be a constant quantity. Their specific heat of certain
metals differ greatly from what is found by others. For instance, they
make the specific heat of lead .0293; the lowest authority I have
seen is Crawford, .0352, and the highest Kirwan .050; from repeated
trials I have lately found it, upon an average, .032. The weights of
some of the atoms in their table, differ materially from what are
commonly received; for instance, bismuth is 13.3 instead of 9; also
copper, silver, and cobalt, are only half the weights of some authors.
The gases too are unfortunate examples. Oxygen gas gives a product of
.236 instead of .375; azotic gas gives a product .1967, if oxygen be
to azote as 7 to 5, but a product of .393 if oxygen be to azote as 7
to 10: by Dr. Thomson’s ratio of oxygen to azote, 4 to 7, the product
will be .482, very different from .375. Hydrogen will give a product of
.47 or .41 instead of .375. All these differences, it may be said, are
occasioned by errors in the specific heats of the gases; but if errors
of this magnitude can still subsist after all the care that has been
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