A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
taken, we shall scarcely know what to trust in experimental philosophy.
If M. Dulong would assume all his simple elements in an elastic state
and under one uniform pressure, the hypothesis would then make a
part of mine (vol. 1. page 70), and there is great reason to believe
it would be either accurately true or a good approximation; but to
suppose that some of the bodies should be in a solid state, having
their particles united by various degrees of attraction, others fluid,
and others in the elastic state, without any material modifications of
their heat arising from these circumstances, appears to me to be in
opposition to some of the best established phenomena in the mechanical
philosophy.
Their observations on the specific heat of compound elements, on
the relation of the heat developed by combination, as compared with
the heat of the elements before and after the combination, &c., are
not supported by a detail of actual experience. Heat given out by
chemical changes they suppose not to have been previously in a state of
combination with the elements. As an argument, the heat given out by
charcoal kept in a state of ignition, by a current of galvanic fluid,
is adduced. It is true this case is most easily explained, by allowing
that the galvanic fluid is in such circumstances converted into heat.
But the charcoal does not undergo any chemical change, and therefore
this is not a case in point.
All modern experience concurs in shewing that the heat of combustion
is primarily dependent on the quantity of oxygen combining. The heat
evolved by the combustion of phosphorus and hydrogen is very nearly,
if not accurately, in proportion to the oxygen spent. The heat by the
combustion of charcoal is not in a much less ratio: and I find the heat
in burning carbonic oxide, carburetted hydrogen and olefiant gas is the
same as in burning hydrogen gas, _provided the combining oxygen is the
same_.
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